Publications

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Peer Reviewed Journal Articles 

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In press/submitted
[158]Quasi-Monodisperse Polymer Libraries via Flash Column Chromatography: Correlating Dispersity with Glass Transition 
 J. J. Haven, T. Junkers, submitted.

[157]Magnetic Force Microscopy of in a Polymer Matrix Embedded Single Magnetic Nanoparticles 
 A. Krivcov, J. Schneider, T. Junkers, H. Möbius, submitted.

[156]Laser-grafted Molecularly Imprinted Polymers for the Detection of Histamine From Organocatalyzed Atom Transfer Radical Polymerization 
 G. Ramakers, G. Wackers, V. Trouillet, A. Welle, P. Wagner, T. Junkers, submitted.

[155]Mapping Dithiobenzoate-Mediated RAFT Polymerization Products via Online Microreactor/Mass Spectrometry Monitoring 
 J. J. Haven, T. Junkers, polymers 2018, accepted.

[154]Synthesis of functional polymer particles from Morita-Baylis-Hillman polymerization 
 G. Ramakers, C. D'Incal, M. Gagliardi, D. Molin, T. Junkers, Macromol. Rapid. Commun. 2018, accepted.

[153]Ultra-precise polymer synthesis via autonomous self-optimizing flow reactors 
 M. Rubens, J.H. Vrijsen, J. Laun, T. Junkers, Angew. Chem. Int. Ed. 2018, accepted.

[152]Ultrafast PhotoRAFT Block Copolymerization of Isoprene and Styrene Facilitated Through Continuous Flow Operation 
 F. Lauterbach, M. Rubens, V. Abetz, T. Junkers, Angew. Chem. Int. Ed. 2018, accepted.

[151] Reactor Automation in Continuous Flow Polymerisation: On-Demand Delivery of Precision Polymer Materials 
  J. J. Haven, T. Junkers, Chemistry Today, 2018, accepted.

[150]Sequence-Definition from Controlled Polymerization: The Next Generation of Materials  
 J. De Neve, J. Haven, L. Maes, T. Junkers, Polym. Chem. 2018, accepted.

[149]Understanding electrostatic and magnetic forces in magnetic force microscopy: towards single superparamagnetic nanoparticle resolution  
 A. Krivkov, T. Junkers, H. Moebius, J. Phys. Comm, 2018, accepted.

[148]Micro-Patterned Molecularly Imprinted Polymer Structures on Functionalized Diamond-Coated Substrates for Testosterone Detection  
 E. Kellens, H. Bove, T. Vandenryt, J. Dekens, j. Lambrichts, S. Drijkoningen, J. D'Haen, W. De Ceuninck, R. Thoelen, T. Junkers, K. Haenen, A. Ethirajan, Biosens. Bioelectron. 2018, accepted.
[147] Visible Light-Mediated Polymerization-Induced Self-Assembly using Continuous Flow Reactors 
  N. Zaquen, J. Yeow, T. Junkers, C. Boyer, P.B. Zetterlund, Macromolecules 2018, in press.

[146] Size-Dependent Properties of Functional PPV-based Conjugated Polymer Nanoparticles for Bioimaging 
  M. Peters, S. Seneca, N. Hellings, T. Junkers, A. Ethirajan, Colloids Surf. B: Biointerfaces 2018, 169, 494-501.
[145] PEGylation of Functional PPV-Based Conjugated Polymer Nanoparticles: Implications on the Synthetic and Biological Identity 
  M. Peters, D. Desta, G. Reekmans, P. Adriaensens, J.-P. Noben, N. Hellings, T. Junkers, A. Ethirajan, Biomacromolecules 2018,17, 2562-2571.

[144] Reversible Surface Engineering via Nitrone-Mediated Radical Coupling
  J. Laun, W. Marchal, V. Troulliet, A. Welle, A. Hardy, M.K. van Bael, C. Barner-Kowollik, T. Junkers, Langmuir 2018, 34, 3244-3255.
[143] 2D laser lithography on silicon substrates via photoinduced copper-mediated radical polymerization
  J. Laun, Y. De Smet, E. Van de Reydt, A. Krivcov, V. Trouillet, A. Welle, H. Moebius, C. Barner-Kowollik, T. Junkers, Chem. Commun. 2018, 54, 751-754.

[142] Direct synthesis of acrylate monomers in heterogeneous continuous flow processes
  J. Salaklang, V. Maes, M. Conradi, R. Dams, T. Junkers, React. Chem. Eng. 2018, 2, 41-47.
[141] Precise Macromolecular Engineering via Continuous-Flow Synthesis Techniques
 
T. Junkers, J. Flow. Chem, 2018, 7, 106-110.
2017
 
[140] Photo-induced ring-closure via a looped flow reactor
 
E. Baeten, M. Rubens, K. N. R. Wuest, C. Barner-Kowollik, T. Junkers, React. Chem. Eng. 2017, 2, 826-829.
[139] Visible light-induced iniferter polymerization of methacrylates enhanced by continuous flow
  M. Rubens, P. Latsrisaeng, T. Junkers, Polym. Chem. 2017, 8, 6496-6505. (see Journal Cover Page)
[138]
 Organocatalyzed Photo-Atom Transfer Radical Polymerization of Methacrylic Acid in Continuous Flow and Surface Grafting
  G. Ramakers, A. Krivcov, V. Trouillet, A. Welle, H. Möbius, T. Junkers, Macromol. Rapid Commun. 2017, 38, 1700423.
[137]
 Online Monitoring of Polymerizations: Current Status
  J. Haven, T. Junkers, Eur. J. Org. Chem, 2017, 6474-6482.
[136]
 RAFT Multiblock Reactor Telescoping: From Monomers to Tetrablock Copolymers in a Continuous Multistage Reactor Cascade
  E. Baeten, J.J. Haven, T. Junkers, Polym. Chem. 2017, 8, 3815-3824.
[135]
 
J. J. Haven, J. A. De Neve, T. Junkers, ACS Macro Lett. 2017, 6, 743–747.
[134] The Kinetics of n-Butyl Acrylate Radical Polymerization Revealed in a Single Experiment by Real Time On-line Mass Spectrometry Monitoring
  J. J. Haven, N. Zaquen, M. Rubens, T. Junkers, Macromol. React. 2017, 1700016.(see Journal Cover Page)
[133]
 Kinetic Monte Carlo Generation of Complete Electron Spray Ionization Mass Spectra for Acrylate Macromonomer Synthesis
  P. H. M. Van Steenberge, J. Vandenbergh, M-F. Reyniers, T. Junkers, D.R. D'Hooge, G. B. Marin, Macromolecules 2017, 50, 2625-2636.
[132] Facile photo-flow synthesis of branched poly(butyl acrylate)s
  O. Eckardt, B. Wenn, P. Biehl, T. Junkers, F. H. Schacher, React. Chem. Eng. 2017, 2, 479-486.
[131] High-Throughput Polymer Screening in Microreactors: Boosting the Passerini Three Component Reaction
 
J. J. Haven, E. Baeten, J. Claes,  J. Vandenbergh  and T. Junkers, Polym. Chem 2017, 8, 2972-2978.
[130] Precision Polymer Design in Microstructured Flow Reactors: Improved Control and First Upscale at Once 
  T. Junkers, Macromol. Chem. Phys 2017, 218, 1600421.
[129] Critically evaluated rate coefficients in radical polymerization - 8. Propagation rate coefficients for vinyl acetate in bulk
  C. Barner-Kowollik, S. Beuermann, M. Buback, R.A. Hutchinson, T. Junkers, H. Kattner, B. Manders,  A.N. Nikitin, G.T. Russell, A.M. van Herk, Macromol. Chem. Phys 2017, 218, 1600357.

 
[128] Continuous Microflow PhotoRAFT Polymerization
  B. Wenn, T. Junkers, Macromolecules 2016, 49, 6888-6895.
[127] Advanced Polymer Flow Synthesis
  T. Junkers, R. Hoogenboom, Eur. Polym. J. 2016, 80, 175-176.

[126] Photo-Induced Copper-Mediated Acrylate Polymerization in Continuous Flow Reactors
  S. Railian, B. Wenn, T. Junkers, J. Flow Chem. 2016, 6, 260-267.
[125] PPV Based Conjugated Polymer Nanoparticles as a Versatile Bioimaging Probe: A Closer Look at the Inherent Optical Properties and Nanoparticle-Cell Interactions
  M. Peters, N. Zaquen,  L. D'Olieslaeger, H. Bové, D. Vanderzande, N. Hellings, T. Junkers, A. Ethirajan, Biomacromolecules 2016,17 (8), 2562-2571. (see Journal Cover Page)
[124] Non-crosslinked Profluorescent PPV-based Micellar Systems as a Versatile Theranostic Probe
  N. Zaquen, H. Lu, T. Chang, R. Mamdooh, L. Lutsen, D. Vanderzande, M. Stenzel, T. Junkers, Biomacromolecules 2016, 17, 4068-4094.
[123] Modifiable Poly(p-Phenylene Vinylene) Copolymers Towards Functional Conjugated Materials 
  N. Zaquen, K. Verstraete, L. Lutsen, D. Vanderzande, T. Junkers, Polym. Chem. 2016, 7, 4771-4781.
[122] Photomediated Controlled Radical Polymerization
  X. Pan, M. A. Tasdelen, J. Laun, T. Junkers, Y. Yagci, K. Matyjaszewski, Prog. Polym. Sci. 2016, 62, 73-125.
[121] Efficient Multiblock Starpolymer Synthesis from Photo-Induced Copper-Mediated Polymerization with up to 21 Arms
  B. Wenn, A. Martens, Y. Chuang, J. Gruber, T. Junkers, Polym. Chem. 2016, 7, 2720-2727.
[120] Acid-Induced Room Temperature RAFT Polymerization: Synthesis and Mechanistic Insights
  J. Vandenbergh, B. Schweitzer-Chaput, M. Klussmann, T. Junkers, Macromolecules, 49, 4124-4135.
[119] Anionic Flow Polymerizations Towards Functional Polyphosphoesters in Microreactors: Polymerization and UV-modification
  E. Baeten, S. Vanslambrouck, C. Jerome, P. Lecomte, T. Junkers, Eur. Polym. J., 2016, 80, 208-218.
[118] Kilohertz Pulsed-Laser-Polymerization: Simultaneous Determination of Backbiting, Secondary and Tertiary Radical Propagation Rate Coefficients for tert-Butyl Acrylate
  B. Wenn, T. Junkers, Macromol. Rapid Commun. 2016, 37, 781-787.
[117] Controlled/Living Polymerization Towards Functional Poly(p-phenylene vinylene) Materials 
  N. Zaquen, L. Lutsen, D. Vanderzande, T. Junkers, Polym. Chem. 2016, 7, 1355-1367.
[116] Improved molecular imprinting based on colloidal particles made from miniemulsion: a case study on testosterone and its structural analogues 
  E. Kellens, H. Bové, M. Conradi, L. D’Olieslaeger, P. Wagner, K. Landfester, T. Junkers, A. Ethirajan, Macromolecules 2016, 49, 2559-2567.
[115] Continuous Photoflow Synthesis of Precision Polymers
  T. Junkers, B. Wenn, React. Chem. Eng. 2016, 1, 60-64.
[114] Determining Free-Radical Propagation Rate Coefficients with High Frequency Lasers: Current Status and Future Perspectives
  K. B. Kockler, A. P. Haehnel, T. Junkers, C. Barner-Kowollik, Macromol. Rapid Commun. 2016, 37, 123-134. (see Journal Cover Page)
[113] UV-induced [2+2] grafting-to reactions for polymer modification of cellulose
  M. Conradi, G. Ramakers, T. Junkers, Macromol. Rapid Commun. 2016, 37, 174-180.


[112] Improved Mechanistic Insights into Radical Sulfinyl Precursor MDMO-PPV Synthesis by Combining Microflow Technology and Computer Simulations
  N. Zaquen, P. H.M. Van Steenberge, D. R. D’hooge, M.-F. Reyniers, G. B. Marin, J. Vandenbergh, L. Lutsen, D. J. M. Vanderzande, T. Junkers, Macromolecules 2015, 48, 894-8306.
[111] Solvent Effects on kp in Organic Media? – Statement to the Response
  A. P. Haehnel, B. Wenn, K. Kockler, T. Bantle, A. M. Misske, F. Fleischhaker, T. Junkers, C. Barner-Kowollik, Macromol. Rapid Commun. 2015, 36, 1984-1986.
[110] Interfacial thiol-isocyanate reactions for functional nanocarriers: A facile route towards tunable morphologies and hydrophilic payload encapsulation
  S. Kuypers, S. K. Pramanika, L. D'Olieslaeger, G. Reekmans, M. Peters, J. D'Haen, D. Vanderzande, T. Junkers, P. Adriaensens, A. Ethirajan, Chem. Commun. 2015, 51, 15858-15861.
[109] Improved Livingness and Control over Branching in RAFT Polymerization of Acrylates: Could Microflow Synthesis Make the Difference?
  P. Derboven, P. H. M. Van Steenberge, J. Vandenbergh, M.-F. Reyniers, T. Junkers, D. R. D’hooge, G. B. Marin, Macromol. Rapid Commun. 2015, 36, 2149-2155. (see Journal Cover Page)
[108] Synthesis of Degradable Multi-Segmented Polymers via Michael-Addition Thiol-Ene Step-Growth Polymerization
  J. Vandenbergh, G. Ramakers, L. Van Lokeren, G. Van Assche, T. Junkers, RSC Adv. 2015, 5, 81920 - 81932.
[107] Combustion deposition of MoO3 films: from fundamentals to OPV applications
  W. Marchal, C. De Dobbelaere, J. Kesters, G. Bonneux, J. Vandenbergh, H. Damm, T. Junkers, W. Maes, J. D'Haen, M. Van Bael, A. Hardy, RSC Adv. 2015, 5, 91349 - 91362.
[106] PPV Polymerization via the Gilch Route: Diradical Character of Monomers
  J. Ð. Nikolic, S. Wouters, J. Romanova,  A. Shimizu, B. Champagne, T. Junkers, D. Vanderzande, D. Van Neck, M. Waroquier, V. Van Speybroeck, S. Catak, Chem. Eur. J. 2015, 21, 19176-19185.
[105] Synthesisof Sequence-Defined Acrylate Oligomers via Photoinduced Copper-Mediated Radical Single Unit Monomer Insertions
  J. Vandenbergh, G. Reekmans, P. Adriaensens, T. Junkers, Chem. Sci. 2015, 6, 5753-5761.
[104] Ligand Switch in Photoinduced Copper-Mediated Polymerization: Synthesis of acrylate-methacrylate block copolymers
  Y. Chuang, B. Wenn, S. Gielen, A. Ethirajan T. Junkers, Polym. Chem. 2015, 6, 6488-6497.
[103] Continuous Poly(2-oxazoline) Triblock Copolymer Synthesis in a Microfluidic Reactor Cascade
  E. Baeten, B. Verbraeken, R. Hoogenboom, T. Junkers, Chem. Commun. 2015, 51, 11701-11704.
[102] Photoinduced acrylate polymerization: Unexpected reduction in chain branching
  B. Wenn, G. Reekmans, P. Adriaensens, T. Junkers, Macromol. Rapid Commun. 2015, 36, 1479-1485. (see Journal Cover Page)
[101] Surface Grafting via Photo-induced Copper-mediated Radical Polymerization at Extremely Low Catalyst Concentrations
  J. Laun, M. Vorobii, A. de los Santos Pereira, O. Pop-Georgievski, V. Trouillet, A. Welle, C. Barner-Kowollik, C. Rodriguez-Emmenegger, T. Junkers, Macromol. Rapid Commun. 2015, 36, 1681-1686. (see Journal Cover Page)
[100] Improved Photo-Induced Cobalt-Mediated Radical Polymerization in Continuous Flow Photoreactors
  A. Kermagoret, B. Wenn, A. Debuigne, C. Jérôme, T. Junkers, C. Detrembleur, Polym. Chem. 2015, 5, 3847-3857.
[099] Efficiency Assessment on Single Unit Monomer Insertion Reactions for Monomer Sequence Control: Kinetic Simulations and Experimental Observations
  J. J. Haven, J. Vandenbergh, R. Kurita, J. Gruber, T. Junkers, Polym. Chem. 2015, 6, 5752-5765.
[098] Facile Synthesis of Well-Defined MDMO-PPV Containing (Tri)Block - Copolymers via Controlled Radical Polymerization and CuAAC Conjugation
  N. Zaquen, J. Vandenbergh, M. Schneider-Baumann, L. Lutsen, D. Vanderzande, T. Junkers, Polymers 2015, 7, 418-452.
[097] Continuous Synthesis and Thermal Elimination of Sulfinyl Precursor MDMO-PPV in Consecutive Flow Reactions
  N. Zaquen, E. Baeten, J. Vandenbergh, L. Lutsen, D. Vanderzande, T. Junkers, Chem. Eng. Technol. 2015, 38, 1749-1757.
[096] Watching Polymers Grow: Real Time Monitoring of Polymerizations via an On-line ESI-MS/Microreactor Coupling
  J. J. Haven, J. Vandenbergh, T. Junkers, Chem. Commun. 2015, 51, 4611-4614.
[095] [2+2] Photo-Cycloadditions for Polymer Modification and Surface Decoration
  T. Junkers, Eur. Polym. J., 2015, 65, 273-280. 



[094] Solvent Effects on kp in Organic Media? - A Systematic PLP-SEC Study
  A. P. Haehnel, B. Wenn, K. Kockler, T. Bantle, A. M. Misske, F. Fleischhaker, T. Junkers, C. Barner-Kowollik, Macromol. Rapid Commun., 2014, 35, 2029-2037.

[093] Direct Access to Dithiobenzoate RAFT Agent Fragmentation Rate Coefficients by ESR Spin-Trapping
  K. Ranieri, G. Delaittre, C. Barner-Kowollik, T. Junkers, Macromol. Rapid Commun., 2014, 35, 2023-2028.

[092] Fast and Efficient [2 + 2] UV Cycloaddition for Polymer Modification via Flow Synthesis
  M. Conradi, T. Junkers, Macromolecules, 2014, 47, 5578-5585.
[091] Alpha and Omega: Importance of the Nonliving Chain End in RAFT Multiblock Copolymerization
  J. Vandenbergh, T. Junkers, Macromolecules, 2014, 47, 5051-5059.
[090] Photoinduced Sequence-Controlled Copper-Mediated Polymerization: Synthesis of Decablock Copolymers
  Y. Chuang, A. Ethirajan T. Junkers, ACS Macro Lett., 2014, 3, 732-737.
[089] Thermal detection of histamine with a graphene oxide based molecularly imprinted polymer platform prepared by reversible addition–fragmentation chain transfer polymerization
  M. Peeters, S. Kobben, K.L. Jimenez-Monroy, L. Modesto, M. Kraus, T. Vandenryt, A. Gaulke, B. van Grinsven, S. Ingebrandt, T. Junkers, P. Wagner, Sens. Actuators B: Chem. 2014, 203, 527-535.
[088] Synthesis of Degradable Poly(Methyl Methacrylate) Star Polymers via RAFT Copolymerization with Cyclic Ketene Acetals
  S. Kobben, A. Ethirajan, T. Junkers, J. Polym. Sci. Polym. Chem. 2014, 52, 1633-1641. (see Journal Cover Page)
[087] Cross-linked degradable poly(β-thioester) networks via amine-catalyzed thiol-ene click polymerization
  J. Vandenbergh, M. Peeters, T. Kretschmer, P. Wagner, T. Junkers, Polymer 2014, 55, 3525–3532.
[086] Synthesis of PPV-b-PEG block copolymers via CuAAC conjugation
  I. Cosemans, J. Vandenbergh, L. Lutsen, D. Vanderzande, T. Junkers, Eur. Polym. J. 2014, 55, 114-122.
[085] Photo-Induced Copper-Mediated Polymerization of Methyl Acrylate in Continuous Flow Reactors
  B. Wenn, M. Conradi, A. Demetrio Carreiras, D. Haddleton, T. Junkers, Polym. Chem. 2014, 5, 3053-3060.
[084] Polymer end group modifications and polymer conjugations via click chemistry employing microreactor technology
  J. Vandenbergh, T. Tura, E. Baeten, T. Junkers, J. Polym. Sci. Polym. Chem. 2014, 52, 1263-1274.
[083] Nitrone-Mediated Radical Coupling of Polymers Derived from Reverse Iodine-Transfer Polymerization
  K. Ranieri, J. Vandenbergh, C. Barner-Kowollik, T. Junkers, Macromol. Chem. Phys. 2014, 215, 1991-2000.
[082] Facile design of biodegradable poly(beta-thioester)s with tunable structure and functionality
  N. Zaquen, B, Wenn, K. Ranieri, J. Vandenbergh, T. Junkers, J. Polym. Sci. Polym. Chem. 2014, 52, 178-187. (see Journal Cover Page)
[081] Critically Evaluated Rate Coefficients in Radical Polymerization - 7. Secondary-Radical Propagation Rate Coefficients for Methyl Acrylate in Bulk
  C. Barner-Kowollik, S. Beuermann, M. Buback, P. Castignolles, B. Charleux, M.L. Coote, R.A. Hutchinson, T. Junkers, I. Lacík, G.T. Russell, M. Stach, A.M. van Herk, Polym. Chem. 2014, 5, 204-212.

[080] Straightforward Synthesis of Symmetrical Multiblock Copolymers by Simultaneous Block Extension and Radical Coupling Reactions
  A. Debuigne, C. Detrembleur, C. Jerome, T. Junkers, Macromolecules 2013, 46, 8922-8931.
[079] Synthesis of Sequence-Controlled Acrylate Oligomers via Consecutive RAFT Single Monomer Insertions
  J. Vandenbergh, G. Reekmans, P. Adriaensens, T. Junkers, Chem. Commun. 2013, 49, 10358-10360.
[078] Synthesis of Macromonomers from High-Temperature Activation of NMP-made Polyacrylates
  J. Vandenbergh, T. Junkers, Macromolecules 2013, 46, 3324-3331.
[077] Synthesis of well-defined PPV containing block copolymers with precise endgroup control from a dual-initiator strategy
  I. Cosemans, J. Vandenbergh, L. Lutsen, D. Vanderzande, T. Junkers, Polym. Chem. 2013, 4, 3471-3479.
[076] Synthesis of MDMO-PPV nanoparticles via in-situ sulfinyl precursor route polymerization in miniemulsion
  A. Ethirajan, L. D'Olieslaeger, J. Vandenbergh, L. Lutsen, M. D'Olieslaeger, D. Vanderzande, T. Junkers, Macromol. Chem. Phys. 2013, 214, 1859-1864.
[075] Precision Synthesis of Acrylate Multiblock Copolymers from Consecutive Microreactor RAFT Polymerizations
  J. Vandenbergh, T. M. Ogawa, T. Junkers, J. Polym. Sci. Polym. Chem. 2013, 51, 2366-2374. (see Journal Cover Page)
[074] UV-induced functionalization of poly(divinylbenzene) nanoparticles via efficient [2+2] cycloadditions
  A. Ethirajan, L. Baeten, M. Conradi, K. Ranieri, B. Conings, H.-G. Boyen, T. Junkers, Polym. Chem. 2013, 4, 4010-4016.
[073] Efficient [2+2] Photocycloadditions under Equimolar Conditions by Employing a Continuous UV-Flow Reactor
  M. Conradi, T. Junkers, J. Photochem. Photobiol. A 2013, 259, 41-46.
[072] Anionic PPV Polymerization from the Sulfinyl Precursor Route: Block Copolymer Formation from Sequential Addition of Monomers
  I. Cosemans, J. Vandenbergh, V. Voet, K. Loos, L. Lutsen, D. Vanderzande, T. Junkers, Polymer 2013, 54, 1298-1304.
[071] Enhanced Spin Capturing Polymerization of Ethylene
  C. Dommanget, C. Boisson, B. Charleux, F. D’Agosto, V. Monteil, F. Boisson, T. Junkers, C. Barner-Kowollik, Y. Guillaneuf, D. Gigmes, Macromolecules 2013, 46, 29-36.
[070] Transfer Reactions in Phenyl Carbamate Ethyl Acrylate Polymerizations
  F. Bennet, T. Rölle,T. Fäcke, M.-S. Weiser, F.-K. Bruder, C. Barner-Kowollik, T. Junkers, Macromol. Chem. Phys. 2013, 214, 236-245.

[069] Synthesis of (Bio)-Degradable Poly(ß-thioester)s via Amine Catalyzed Thiol-Ene Click Polymerization
  J. Vandenbergh, K. Ranieri, T. Junkers, Macromol. Chem. Phys. 2012, 213, 2611-2617.
[068] Macromonomers from AGET Activation of Poly(n-Butyl Acrylate) Precursors: Radical Transfer Pathways and Midchain Radical Migration
  J. Vandenbergh, T. Junkers, Macromolecules 2012, 45, 6850-6856.
[067] SP-PLP-EPR Investigations into the Termination Kinetics of n-Butyl Acrylate Macromonomers
  J. Barth, M. Buback, C. Barner-Kowollik, T. Junkers, G. T. Russell, J. Polym. Sci. Polym. Chem. 2012, 50, 4740-4748.
[066] Investigation of the Endgroup Fidelity at High Conversion during Nitroxide-Mediated Acrylate Polymerizations
  Y. Guillaneuf, D. Gigmes, T. Junkers, Macromolecules 2012, 45, 5371-5378.
[065] Use of a Continuous-Flow Microreactor for Thiol-Ene Functionalization of RAFT-Derived Poly(Butyl Acrylate)
  J. Vandenbergh, T. Junkers, Polym. Chem. 2012, 3, 2739-2742.
[064] Enhanced Spin Capturing Polymerization and Radical Coupling Mediated by Cyclic Nitrones
  K. Ranieri, M. Conradi, P.-Y. Chavant, V. Blandin, C. Barner-Kowollik, T. Junkers, Aust. J. Chem. 2012, 65, 1110-1116.
[063] Thioketone-Mediated Polymerization with Dithiobenzoates: Proof for the Existence of Stable Radical Intermediates in RAFT Polymerization
  T. Junkers, G. Delaittre, R. Chapman, F. Günzler, E. Chernikova, C. Barner-Kowollik, Macromol. Rapid Commun. 2012, 33, 984-990.
[062] Thermally Responsive Core-shell Microparticles and Cross-Linked Networks Based on Nitrone Chemistry
  L. Barner, A. S. Quick, A. P. Vogt, V. Winkler, T. Junkers, C. Barner-Kowollik, Polym. Chem. 2012, 3, 2266-2276.
[061] A Qualitative and Quantitative Post-Mortem Analysis: Studying Free-Radical Initiation Processes via Soft Ionization Mass Spectrometry
  D. Voll, T. Junkers, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2012, 50, 2739-2757.
[060] Interpolymer radical coupling: a toolbox complementary to controlled radical polymerization
  A. Debuigne, M. Hurtgen, C. Detrembleur, C. Jérôme, C. Barner-Kowollik, T. Junkers, Prog. Polym. Sci. 2012, 37, 1004-1030.
[059] Controlled Synthesis of MDMO-PPV and Block Copolymers Made Thereof
  J. Vandenbergh, I. Cosemans, L. Lutsen, D. Vanderzande, T. Junkers, Polym. Chem. 2012, 3, 1722-1725.
[058] A Living Polymerization Method for the Synthesis of PPV Materials
  I. Cosemans, J. Wouters, W. Maes, T. J. Cleij, L. Lutsen, T. Junkers, D. J. M. Vanderzande, Macromol. Rapid Commun. 2012, 33, 242-247.
[057] Quantifying Photoinitiation Efficiencies in a Multi-Photoinitiated Free Radical Polymerization
  D. Voll, A. Hufendiek, T. Junkers, C. Barner-Kowollik, Macromol. Rapid Commun. 2012, 33, 47-53.
[056] Synthesis of poly(p-phenylene vinylene) materials via the precursor routes
  T. Junkers, J. Vandenbergh, L. Lutsen, P. Adriaensens, D. Vanderzande, Polym. Chem. 2012, 3, 275-285.
[055] Synthesis of Amphiphilic Star and H-Shape Polymers via a Combination of Cobalt-Mediated Radical Polymerization and Nitrone-Mediated Radical Coupling Reactions
  C. Detrembleur, A. Debuigne, O. Altintas, M. Conradi, E.H.H. Wong, C. Jérôme, C. Barner-Kowollik, T. Junkers, Polym. Chem. 2012, 3, 135-147.
[054] Revealing Model Dependencies in “Assessing the RAFT Equilibrium Constant via Model Systems: An EPR Study"
  T. Junkers, C. Barner-Kowollik, M. L. Coote, Macromol. Rapid Commun. 2011, 32, 1891-1898.
[053] Photoinduced Conjugation of Aldehyde Functional Polymers with Olefins via [2+2]-Cycloaddition
  M. Conradi, T. Junkers, Macromolecules 2011, 44, 7969-7976. (see Journal Cover Page)
[052] Formation of Triblock Copolymers via a Tandem Enhanced Spin Capturing – Nitroxide Mediated Polymerization (ESC-NMP) Reaction Sequence
  T. Junkers, L. Zang, E.H.H. Wong, N. Dingenouts, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2011, 49, 4841-4850. (see Journal Cover Page)
[051] Discovery of an anionic polymerization mechanism for high molecular weight PPV derivatives via the sulfinyl precursor route
  I. Cosemans, L. Hontis, D. Van Den Berghe, A. Palmaerts, J. Wouters, W. Maes, T. J. Cleij, L. Lutsen, T. Junkers, D. J. M. Vanderzande, Macromolecules 2011, 44, 7610-7616.
[050] A Detailed Investigation of the Free Radical Copolymerization Behavior of n-Butyl Acrylate Macromonomers
  A.M. Zorn, T. Junkers, C. Barner-Kowollik, Macromolecules 2011, 44, 6691-6700.
[049] RAFT Kinetics Revisited: Revival of the RAFT Debate
  T. Junkers, J. Polym. Sci. Polym. Chem. 2011, 49, 4154-4163.
[048] Quantitative Comparison of the Mesitoyl vs. the Benzoyl Fragment in Photoinitiation: A Question of Origin
  D. Voll, T. Junkers, C. Barner-Kowollik, Macromolecules 2011, 44, 2542-2551.
[047] Embedding Multiple Site-Specific Functionalities into Polymer Chains via Nitrone-Mediated Radical Coupling NMRC) Reactions
  E.H.H. Wong, M.H. Stenzel, T. Junkers, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2011, 49, 2118-2126.
[046] Nitrone-Mediated Radical Coupling (NMRC) Reactions: A New Synthetic Tool Exemplified on Dendrimer Synthesis
  E.H.H. Wong, O. Altintas, M.H. Stenzel, C. Barner-Kowollik, T. Junkers, Chem. Commun. 2011, 47, 5491-5493 (highlighted in Synfacts 2011, 7, 0727)
[045] Nitrones in Synthetic Polymer Chemistry
  E.H.H. Wong, T. Junkers, C. Barner-Kowollik, Polym. Chem. 2011, 2, 1008-1017.
[044] On the Kinetic and Mechanistic Similarity between RAFT Intermediate and Acrylate Midchain Radicals
  C. Barner-Kowollik, T. Junkers, J. Polym. Sci. Polym. Chem. 2011, 49, 1293-1297.
[043] Clicking Polymers or Just Efficient Linking: What Makes the Difference?
  C. Barner-Kowollik, F.E. Du Prez, P. Espeel, C.J. Hawker, T. Junkers, H. Schlaad, W. Van Camp, Angew. Chem. Int. Ed. 2011, 50, 60-62. (Engl. Version) Angew. Chem. 2011, 123, 61-64 (German translation)
[042] Determination of Propagation Rate Coefficients for Methyl and 2-Ethylhexyl Acrylate via High Frequency PLP-SEC under Consideration of the Impact of Chain Branching
  T. Junkers, M. Schneider-Baumann, S.P.S. Koo, P. Castignolles, C. Barner-Kowollik, Macromolecules 2010, 43, 10427-10434.
[041] Control of Methyl Methacrylate Radical Polymerization via Enhanced Spin Capturing Polymerization (ESCP)
  L. Zang, E.H.H. Wong, C. Barner-Kowollik, T. Junkers, Polymer 2010, 51, 3821-3825.
[040] Reducing the Degree of Branching in Polyacrylates via Mid-Chain Radical Patching: A Quantitative Melt-State NMR Study
  M. Gaborieau, S.P.S. Koo, P. Castignolles, T. Junkers, C. Barner-Kowollik, Macromolecules 2010, 51, 5492-5495.
[039] Determination of the Propagation Rate Coefficient of Acrylonitrile
  T. Junkers, S.P.S. Koo, C. Barner-Kowollik, Polym. Chem. 2010, 1, 438-441.
[038] Detailed Investigation of the Propagation Rate of Urethane Acrylates
  C. Barner-Kowollik, F. Bennet, M. Schneider-Baumann, D. Voll, T. Rölle, T. Fäcke, M.S. Weiser, F.K. Bruder, T. Junkers, Polym. Chem. 2010, 1, 470-479.
[037] Spin Capturing with ‘Clickable’ Nitrones: Generation of Mikto-Armed Star Polymers
  E.H.H. Wong, M.H. Stenzel, T. Junkers, C. Barner-Kowollik, Macromolecules 2010, 43, 3785-3793.
[036] Spin Capturing with Nitrones: Radical Coupling Reactions with Concurrent Introduction of Midchain Functionality
  E.H.H. Wong, C. Boyer, M.H. Stenzel, C. Barner-Kowollik, T. Junkers, Chem. Commun. 2010, 46, 1959-1961.
[035] Limitations of Radical Thiol-ene Reactions for Polymer-Polymer Conjugation
  S.P.S. Koo, M.M. Stamenovic, R.A. Prasath, A.J. Inglis, F.E. Du Prez, C. Barner-Kowollik, W. Van Camp, T. Junkers, J. Polym. Sci. Polym. Chem. 2010, 48, 1699-1713. (see Journal Cover Page)
[034] Mark Houwink Parameters for the Universal Calibration of Acrylate, Methacrylate and Vinyl Acetate Polymers Determined by Online Size-Exclusion Chromatography – Mass Spectrometry
  T. Gruendling, T. Junkers, M. Guilhaus, C. Barner-Kowollik, Macromol. Chem. Phys. 2010, 211, 520-528.
[033] Synthesis of a Macromonomer Library from High-Temperature Acrylate Polymerization
  A.M. Zorn, T. Junkers, C. Barner-Kowollik, Macromol. Rapid Commun. 2009, 30, 2028-2035.
[032] Continuous ATRP Synthesis of Block-like Copolymers via Column Reactors: Design and Validation of a Kinetic Model
  B. Dervaux, T. Junkers, C. Barner-Kowollik, F.E. Du Prez, Macromol. React. Eng. 2009, 3, 529-538.
[031] Propagation Rate Coefficients of Isobornyl Acrylate, tert-Butyl Acrylate and 1-Ethoxyethyl Acrylate: A High Frequency PLP-SEC Study
  B. Dervaux, T. Junkers, M. Schneider-Baumann, F.E. Du Prez, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2009, 47, 6641-6657.
[030] Optimum Reaction Conditions for the Synthesis of Macromonomers via High-Temperature Polymerization of Acrylates
  T. Junkers, C. Barner-Kowollik, Macromol. Theory Simul. 2009, 18, 421-433. (see Article Frontpiece)
[029] Formation Efficiency of ABA Blockcopolymers via Enhanced Spin Capturing Polymerization (ESCP): Locating the Alkoxyamine Function
  T. Junkers, E.H.H. Wong, M.H. Stenzel, C. Barner-Kowollik, Macromolecules 2009, 18, 421-433.
[028] Free-Radical Propagation and Termination Kinetics of the Butyl Acrylate Dimer Studied by Pulsed Laser Polymerization Techniques
  M. Buback, T. Junkers, M. Müller, Polymer 2009, 50, 3111-3118.
[027] Determination of Vinyl Acetate Propagation Rate Coefficients via High Frequency Pulsed Laser Polymerization
  T. Junkers, D. Voll, C. Barner-Kowollik, e-polymers 2009, 076.
[026] Quantifying the Efficiency of Photo-Initiation Processes in Methyl Methacrylate Free Radical Polymerization via Electrospray Ionization Mass Spectrometry
  F. Günzler, E.H.H. Wong, S.P.S. Koo, T. Junkers, C. Barner-Kowollik, Macromolecules 2009, 42, 1488-1493.
[025] Studying the Mechanism of Thioketone Mediated Polymerization (TKMP) via Electrospray Ionization Mass Spectrometry
  F. Günzler, T. Junkers, C. Barner-Kowollik, C, J. Polym. Sci. Polym. Chem. 2009, 47, 1864-1876.
[024] The Kinetics of Enhanced Spin Capturing Polymerization (ESCP): Influence of the Nitrone Structure
  E.H.H. Wong, M.H. Stenzel, T. Junkers, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2009, 47, 1098-1107.
[023] Quantitative Product Spectrum Analysis of Poly(Butyl Acrylate) via Electrospray Ionization Mass Spectrometry
  S.P.S. Koo, T. Junkers, C. Barner-Kowollik, Macromolecules 2009, 42, 62-69.
[022] Pushing the Limit: Pulsed Laser Polymerization of Butyl Acrylate at 500 hz
  C. Barner-Kowollik, F. Günzler, T. Junkers, Macromolecules 2008, 41, 8971-8973.
[021] A Study into the Stability of 3,6-Dihydro-2H-thiopyran Rings: Key Linkages in the RAFT Hetero Diels-Alder Click Concept
  S. Sinnwell, C.V. Synatschke, T. Junkers, M.H. Stenzel, C. Barner-Kowollik, Macromolecules 2008, 41, 7904-7912.
[020] The Role of Mid-chain Radicals in Acrylate Free Radical Polymerization: Branching and Scission
  T. Junkers, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2008, 46, 7585-7605. (see Journal Cover Page)
[019] Enhanced Spin Capturing polymerization: An Efficient and Versatile protocol for Controlling Molecular Weight Distributions
  E.H.H. Wong, T. Junkers, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2008, 146, 7273-7279.
[018] Controlling the Fate of Midchain Radicals in Acrylate Polymerization
  T. Junkers, J. Polym. Sci. Aust. J. Chem. 2008, 61, 646.
[017] Self-Directed Formation of Uniform Unsaturated Macromolecules from Acrylate Monomers at High Temperatures
  T. Junkers, F. Bennet, S.P.S. Koo, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2008, 46, 3433-3437.
[016] Laser Induced Marking of Polymer Chains with Radical Spin Traps
  T. Junkers, E.H.H. Wong, Z. Szablan, T.P. Davis, M.H. Stenzel, C. Barner-Kowollik, Macromol. Rapid. Commun. 2008, 29, 503-510.
[015] PLP labelling in ESR spectroscopic Analysis of Secondary and Tertiary Acrylate Propagating Radicals
  M. Buback, P. Hesse, T. Junkers, T. Sergeeva, T. Theis, Macromolecules 2008, 41, 288-291.
[014] Chain-Length-Dependent Termination in Acrylate Radical Polymerization Studied via Pulsed-Laser-Initiated RAFT Polymerization
  M. Buback, P. Hesse, T. Junkers, T. Theis, P. Vana, P, Aust. J. Chem. 2007, 60, 779-787.
[013] Mapping Poly(butyl acrylate) Product Distributions by Mass Spectrometry in a Wide Temperature Range: Suppression of Midchain Radical Side Reactions
  T. Junkers, S.P.S. Koo, M.H. Stenzel, T.P. Davis, C. Barner-Kowollik, Macromolecules 2007, 40, 8906-8912.
[012] Mapping Photolysis Product Radical Reactivities via Soft Ionization Mass Spectrometry in Acrylate, Methacrylate and Itaconate Systems
  Z. Szablan, T. Junkers, S.P.S. Koo, T.M. Lovestead, M.H. Stenzel, T.P. Davis, C. Barner-Kowollik, Macromolecules 2007, 40, 6820-6833.
[011] Thioketone–Mediated Polymerization of Butyl Acrylate: Controlling Free-Radical Polymerization via a Dormant Radical Species
  T. Junkers, M.H. Stenzel, T.P. Davis, C. Barner-Kowollik, Macromol. Rapid Commun. 2007, 28, 746-753.
[010] Termination Kinetics of tert-Butyl Methacrylate and of n-Butyl Methacrylate Free-Radical Bulk Homopolymerizations
  M. Buback, T. Junkers, Macromol. Chem. Phys. 2006, 207, 1640-1650.
[009] Determination of Addition and Fragmentation Rate Coefficients in RAFT Polymerization via Time-Resolved ESR Spectroscopy after Laser Pulse Initiation
  M. Buback, P. Hesse, T. Junkers, P. Vana, Macromol. Rapid Commun. 2006, 27, 182-187.
[008] Mechanism of Poly(Methyl Methacrylate) Film Growth During Pulse Laser Deposition
  E. Süske, T. Scharf, T. Junkers, M. Buback, H.U. Krebs, J. Appl. Phys. 2006, 10, No. 014906.
[007] Free-Radical Polymerization Kinetics of 2-Acrylamido-2-Methylpropane­Sulfonic Acid in Aqueous Solution
  S. Beuermann, M. Buback, P. Hesse, T. Junkers, I. Lacík, Macromolecules 2006, 39, 509-516.
[006] Chain Length Dependent Termination in Butyl Acrylate Free–Radical Polymerization Studied via Stationary and Pulsed Laser Initiated RAFT Polymerization
  T. Junkers, A. Theis, M. Buback, T.P. Davis, M.H. Stenzel, P. Vana, C. Barner-Kowollik, Macromolecules 2005, 38, 9497-9508.
[005] Laser Single Pulse Initiated RAFT Polymerization for Assessing Chain-Length Dependent Radical Termination Kinetics
  M. Buback, T. Junkers, P. Vana, Macromol. Rapid Commun. 2005, 26, 796-802.
[004] PLP-ESR Monitoring of Mid-chain Radicals in n-Butyl Acrylate Polymerization
  R.X.E. Willemse, A.M. van Herk, E. Panchenko, T. Junkers, M. Buback, Macromolecules 2005, 38, 5098-5103.
[003] Tuning of Cross-Linking and Mechanical Properties of Laser Deposited Poly(Methyl Methacrylate) Films
  E. Süske, T. Scharf, H.U. Krebs, E. Panchenko, T. Junkers, M. Egorov, M. Buback, H. Kijewski, H., J. Appl. Phys. 2005, 97, No. 063501.
[002] Termination Kinetics of di-n-Butyl Itaconate Free-Radical Polymerization Studied via the SP-PLR-ESR Technique
  M. Buback, M. Egorov, T. Junkers, E. Panchenko, Macromol. Chem. Phys. 2005, 206, 333-341.(see Journal Cover Page)
[001] Free-Radical Termination Kinetics Studied Using a Novel SP-PLP-ESR Technique
  M. Buback, M. Egorov, T. Junkers, E. Panchenko, Macromol. Rapid Commun. 2004, 25, 1004-1009.