Peer Reviewed Journal Articles
In press/submitted
| [165] | Micellar self-assembly in continuous flow: influence of mixing parameters and in-line purification | | | A.-L. Buckinx, K. Verstraete, E. Baeten, R. Tabor, A. Sokolova, N. Zaquen, T. Junkers, submitted.
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| [164] | Aqueous RAFT Photo Polymerization-Induced Self-Assembly of Acrylamides: Scalable and Direct Nanoparticles Access via Flow Chemistry | | | N. Zaquen, H. Zhu, N. Najib, T. Junkers, P.B. Zetterlund, C. Boyer, submitted.
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| [163] | Photoiniferter surface grafting of poly(methyl acrylate) using xanthates | | | G. Ramakers, M. Rubens, A. Krivcov, H. Möbius, V. Trouillet, A. Welle, T. Junkers, submitted.
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| [162] | Alcohol-based PISA in Batch and Flow: Exploring the Role of Photoinitiators | | | N. Zaquen, W. Azizi, J. Yeow, R. P. Kuchel, T. Junkers, C. Boyer, P.B. Zetterlund, submitted.
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| [161] | Continuous Flow Synthesis of Core Cross-Linked Star Polymers via Photo-Induced Copper Mediated Polymerization | | | J. H. Vrijsen, C. O. Meideiros, J. Gruber, T. Junkers, Polym. Chem. 2019, accepted.
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| [160] | Scalable Synthesis of Sequence-Defined Oligomers via Photoflow Chemistry | | | M. Van de Walle, K. De Bruycker, T. Junkers, J. P. Blinco, C. Barner-Kowollik, ChemPhotoChem 2019, accepted.
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| [159] | Learning from Peptides to Access Functional Precision Polymer Sequences | | | E. Maron, J. H. Swisher, J. J. Haven, T. Y. Meier, T. Junkers, H. G. Boerner, submitted..
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| [158] | Rapid Oxygen Tolerant Aqueous RAFT Photopolymerization in Continuous Flow Reactors | | | N. Zaquen, A.Kadir, A. Iasa, N. Corrigan, T. Junkers, P. B. Zetterlund, C. Boyer, Macromolecules 2019, accepted.
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| [157] | Quasi-Monodisperse Polymer Libraries via Flash Column Chromatography: Correlating Dispersity with Glass Transition | | | J. J. Haven, T. Junkers, Polym. Chem 2019, accepted.
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| [156] | Magnetic Force Microscopy of in a Polymer Matrix Embedded Single Magnetic Nanoparticles | | | A. Krivcov, J. Schneider, T. Junkers, H. Möbius, Phys. Stat Sol. 2019, accepted.
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| [155] | Laser-grafted Molecularly Imprinted Polymers for the Detection of Histamine From Organocatalyzed Atom Transfer Radical Polymerization | | | G. Ramakers, G. Wackers, V. Trouillet, A. Welle, P. Wagner, T. Junkers, Macromolecuels 2019, accepted.
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| [154] | Ultra-precise polymer synthesis via autonomous self-optimizing flow reactors | | | M. Rubens, J.H. Vrijsen, J. Laun, T. Junkers, Angew. Chem. Int. Ed. 2019, accepted.
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| [153] | Mapping Dithiobenzoate-Mediated RAFT Polymerization Products via Online Microreactor/Mass Spectrometry Monitoring | | | J. J. Haven, T. Junkers, polymers 2018, accepted.
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| [152] | Synthesis of functional polymer particles from Morita-Baylis-Hillman polymerization | | | G. Ramakers, C. D'Incal, M. Gagliardi, D. Molin, T. Junkers, Macromol. Rapid. Commun. 2018, accepted.
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| [151] | Ultrafast PhotoRAFT Block Copolymerization of Isoprene and Styrene Facilitated Through Continuous Flow Operation | | | F. Lauterbach, M. Rubens, V. Abetz, T. Junkers, Angew. Chem. Int. Ed. 2018, accepted.
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| [150] |
Reactor Automation in Continuous Flow Polymerisation: On-Demand Delivery of Precision Polymer Materials |
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J. J. Haven, T. Junkers, Chemistry Today, 2018, accepted.
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| [149] | Sequence-Definition from Controlled Polymerization: The Next Generation of Materials | | | J. De Neve, J. Haven, L. Maes, T. Junkers, Polym. Chem. 2018, accepted.
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| [148] | Understanding electrostatic and magnetic forces in magnetic force microscopy: towards single superparamagnetic nanoparticle resolution | | | A. Krivkov, T. Junkers, H. Moebius, J. Phys. Comm, 2018, accepted.
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| [147] | Micro-Patterned Molecularly Imprinted Polymer Structures on Functionalized Diamond-Coated Substrates for Testosterone Detection | | | E. Kellens, H. Bove, T. Vandenryt, J. Dekens, j. Lambrichts, S. Drijkoningen, J. D'Haen, W. De Ceuninck, R. Thoelen, T. Junkers, K. Haenen, A. Ethirajan, Biosens. Bioelectron. 2018, accepted.
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| [146] |
Visible Light-Mediated Polymerization-Induced Self-Assembly using Continuous Flow Reactors |
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N. Zaquen, J. Yeow, T. Junkers, C. Boyer, P.B. Zetterlund, Macromolecules 2018, in press. |
| [144] |
Reversible Surface Engineering via Nitrone-Mediated Radical Coupling |
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J. Laun, W. Marchal, V. Troulliet, A. Welle, A. Hardy, M.K. van Bael, C. Barner-Kowollik, T. Junkers, Langmuir 2018, 34, 3244-3255.
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| [143] |
2D laser lithography on silicon substrates via photoinduced copper-mediated radical polymerization |
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J. Laun, Y. De Smet, E. Van de Reydt, A. Krivcov, V. Trouillet, A. Welle, H. Moebius, C. Barner-Kowollik, T. Junkers, Chem. Commun. 2018, 54, 751-754.
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2017
| [135] |
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J. J. Haven, J. A. De Neve, T. Junkers, ACS Macro Lett. 2017, 6, 743–747.
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| [134] |
The Kinetics of n-Butyl Acrylate Radical Polymerization Revealed in a Single Experiment by Real Time On-line Mass Spectrometry Monitoring |
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J. J. Haven, N. Zaquen, M. Rubens, T. Junkers, Macromol. React. 2017, 1700016.(see Journal Cover Page)
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[133]
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Kinetic Monte Carlo Generation of Complete Electron Spray Ionization Mass Spectra for Acrylate Macromonomer Synthesis |
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P. H. M. Van Steenberge, J. Vandenbergh, M-F. Reyniers, T. Junkers, D.R. D'Hooge, G. B. Marin, Macromolecules 2017, 50, 2625-2636.
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| [132] |
Facile photo-flow synthesis of branched poly(butyl acrylate)s |
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O. Eckardt, B. Wenn, P. Biehl, T. Junkers, F. H. Schacher, React. Chem. Eng. 2017, 2, 479-486.
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| [131] |
High-Throughput Polymer Screening in Microreactors: Boosting the Passerini Three Component Reaction |
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J. J. Haven, E. Baeten, J. Claes, J. Vandenbergh and T. Junkers, Polym. Chem 2017, 8, 2972-2978.
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| [130] |
Precision Polymer Design in Microstructured Flow Reactors: Improved Control and First Upscale at Once |
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T. Junkers, Macromol. Chem. Phys 2017, 218, 1600421.
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| [129] |
Critically evaluated rate coefficients in radical polymerization - 8. Propagation rate coefficients for vinyl acetate in bulk |
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C. Barner-Kowollik, S. Beuermann, M. Buback, R.A. Hutchinson, T. Junkers, H. Kattner, B. Manders, A.N. Nikitin, G.T. Russell, A.M. van Herk, Macromol. Chem. Phys 2017, 218, 1600357. |
| [125] |
PPV Based Conjugated Polymer Nanoparticles as a Versatile Bioimaging Probe: A Closer Look at the Inherent Optical Properties and Nanoparticle-Cell Interactions |
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M. Peters, N. Zaquen, L. D'Olieslaeger, H. Bové, D. Vanderzande, N. Hellings, T. Junkers, A. Ethirajan, Biomacromolecules 2016,17 (8), 2562-2571. (see Journal Cover Page)
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| [124] |
Non-crosslinked Profluorescent PPV-based Micellar Systems as a Versatile Theranostic Probe |
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N. Zaquen, H. Lu, T. Chang, R. Mamdooh, L. Lutsen, D. Vanderzande, M. Stenzel, T. Junkers, Biomacromolecules 2016, 17, 4068-4094.
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| [117] |
Controlled/Living Polymerization Towards Functional Poly(p-phenylene vinylene) Materials |
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N. Zaquen, L. Lutsen, D. Vanderzande, T. Junkers, Polym. Chem. 2016, 7, 1355-1367.
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| [116] |
Improved molecular imprinting based on colloidal particles made from miniemulsion: a case study on testosterone and its structural analogues |
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E. Kellens, H. Bové, M. Conradi, L. D’Olieslaeger, P. Wagner, K. Landfester, T. Junkers, A. Ethirajan, Macromolecules 2016, 49, 2559-2567.
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| [115] |
Continuous Photoflow Synthesis of Precision Polymers |
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T. Junkers, B. Wenn, React. Chem. Eng. 2016, 1, 60-64.
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| [114] |
Determining Free-Radical Propagation Rate Coefficients with High Frequency Lasers: Current Status and Future Perspectives |
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K. B. Kockler, A. P. Haehnel, T. Junkers, C. Barner-Kowollik, Macromol. Rapid Commun. 2016, 37, 123-134. (see Journal Cover Page)
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| [113] |
UV-induced [2+2] grafting-to reactions for polymer modification of cellulose |
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M. Conradi, G. Ramakers, T. Junkers, Macromol. Rapid Commun. 2016, 37, 174-180.
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| [112] |
Improved Mechanistic Insights into Radical Sulfinyl Precursor MDMO-PPV Synthesis by Combining Microflow Technology and Computer Simulations |
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N. Zaquen, P. H.M. Van Steenberge, D. R. D’hooge, M.-F. Reyniers, G. B. Marin, J. Vandenbergh, L. Lutsen, D. J. M. Vanderzande, T. Junkers, Macromolecules 2015, 48, 894-8306.
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| [111] |
Solvent Effects on kp in Organic Media? – Statement to the Response |
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A. P. Haehnel, B. Wenn, K. Kockler, T. Bantle, A. M. Misske, F. Fleischhaker, T. Junkers, C. Barner-Kowollik, Macromol. Rapid Commun. 2015, 36, 1984-1986.
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| [110] |
Interfacial thiol-isocyanate reactions for functional nanocarriers: A facile route towards tunable morphologies and hydrophilic payload encapsulation |
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S. Kuypers, S. K. Pramanika, L. D'Olieslaeger, G. Reekmans, M. Peters, J. D'Haen, D. Vanderzande, T. Junkers, P. Adriaensens, A. Ethirajan, Chem. Commun. 2015, 51, 15858-15861.
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| [109] |
Improved Livingness and Control over Branching in RAFT Polymerization of Acrylates: Could Microflow Synthesis Make the Difference? |
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P. Derboven, P. H. M. Van Steenberge, J. Vandenbergh, M.-F. Reyniers, T. Junkers, D. R. D’hooge, G. B. Marin, Macromol. Rapid Commun. 2015, 36, 2149-2155. (see Journal Cover Page)
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| [108] |
Synthesis of Degradable Multi-Segmented Polymers via Michael-Addition Thiol-Ene Step-Growth Polymerization |
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J. Vandenbergh, G. Ramakers, L. Van Lokeren, G. Van Assche, T. Junkers, RSC Adv. 2015, 5, 81920 - 81932.
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| [107] |
Combustion deposition of MoO3 films: from fundamentals to OPV applications |
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W. Marchal, C. De Dobbelaere, J. Kesters, G. Bonneux, J. Vandenbergh, H. Damm, T. Junkers, W. Maes, J. D'Haen, M. Van Bael, A. Hardy, RSC Adv. 2015, 5, 91349 - 91362.
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| [106] |
PPV Polymerization via the Gilch Route: Diradical Character of Monomers |
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J. Ð. Nikolic, S. Wouters, J. Romanova, A. Shimizu, B. Champagne, T. Junkers, D. Vanderzande, D. Van Neck, M. Waroquier, V. Van Speybroeck, S. Catak, Chem. Eur. J. 2015, 21, 19176-19185.
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| [105] |
Synthesisof Sequence-Defined Acrylate Oligomers via Photoinduced Copper-Mediated Radical Single Unit Monomer Insertions |
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J. Vandenbergh, G. Reekmans, P. Adriaensens, T. Junkers, Chem. Sci. 2015, 6, 5753-5761.
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| [104] |
Ligand Switch in Photoinduced Copper-Mediated Polymerization: Synthesis of acrylate-methacrylate block copolymers |
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Y. Chuang, B. Wenn, S. Gielen, A. Ethirajan T. Junkers, Polym. Chem. 2015, 6, 6488-6497.
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| [103] |
Continuous Poly(2-oxazoline) Triblock Copolymer Synthesis in a Microfluidic Reactor Cascade |
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E. Baeten, B. Verbraeken, R. Hoogenboom, T. Junkers, Chem. Commun. 2015, 51, 11701-11704.
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| [102] |
Photoinduced acrylate polymerization: Unexpected reduction in chain branching |
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B. Wenn, G. Reekmans, P. Adriaensens, T. Junkers, Macromol. Rapid Commun. 2015, 36, 1479-1485. (see Journal Cover Page)
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| [101] |
Surface Grafting via Photo-induced Copper-mediated Radical Polymerization at Extremely Low Catalyst Concentrations |
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J. Laun, M. Vorobii, A. de los Santos Pereira, O. Pop-Georgievski, V. Trouillet, A. Welle, C. Barner-Kowollik, C. Rodriguez-Emmenegger, T. Junkers, Macromol. Rapid Commun. 2015, 36, 1681-1686. (see Journal Cover Page)
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| [100] |
Improved Photo-Induced Cobalt-Mediated Radical Polymerization in Continuous Flow Photoreactors |
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A. Kermagoret, B. Wenn, A. Debuigne, C. Jérôme, T. Junkers, C. Detrembleur, Polym. Chem. 2015, 5, 3847-3857.
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| [099] |
Efficiency Assessment on Single Unit Monomer Insertion Reactions for Monomer Sequence Control: Kinetic Simulations and Experimental Observations |
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J. J. Haven, J. Vandenbergh, R. Kurita, J. Gruber, T. Junkers, Polym. Chem. 2015, 6, 5752-5765.
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| [098] |
Facile Synthesis of Well-Defined MDMO-PPV Containing (Tri)Block - Copolymers via Controlled Radical Polymerization and CuAAC Conjugation |
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N. Zaquen, J. Vandenbergh, M. Schneider-Baumann, L. Lutsen, D. Vanderzande, T. Junkers, Polymers 2015, 7, 418-452.
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| [097] |
Continuous Synthesis and Thermal Elimination of Sulfinyl Precursor MDMO-PPV in Consecutive Flow Reactions |
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N. Zaquen, E. Baeten, J. Vandenbergh, L. Lutsen, D. Vanderzande, T. Junkers, Chem. Eng. Technol. 2015, 38, 1749-1757.
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| [096] |
Watching Polymers Grow: Real Time Monitoring of Polymerizations via an On-line ESI-MS/Microreactor Coupling |
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J. J. Haven, J. Vandenbergh, T. Junkers, Chem. Commun. 2015, 51, 4611-4614.
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| [095] |
[2+2] Photo-Cycloadditions for Polymer Modification and Surface Decoration |
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T. Junkers, Eur. Polym. J., 2015, 65, 273-280.
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| [094] |
Solvent Effects on kp in Organic Media? - A Systematic PLP-SEC Study |
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A. P. Haehnel, B. Wenn, K. Kockler, T. Bantle, A. M. Misske, F. Fleischhaker, T. Junkers, C. Barner-Kowollik, Macromol. Rapid Commun., 2014, 35, 2029-2037.
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| [093] |
Direct Access to Dithiobenzoate RAFT Agent Fragmentation Rate Coefficients by ESR Spin-Trapping |
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K. Ranieri, G. Delaittre, C. Barner-Kowollik, T. Junkers, Macromol. Rapid Commun., 2014, 35, 2023-2028.
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| [092] |
Fast and Efficient [2 + 2] UV Cycloaddition for Polymer Modification via Flow Synthesis |
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M. Conradi, T. Junkers, Macromolecules, 2014, 47, 5578-5585.
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| [091] |
Alpha and Omega: Importance of the Nonliving Chain End in RAFT Multiblock Copolymerization |
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J. Vandenbergh, T. Junkers, Macromolecules, 2014, 47, 5051-5059.
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| [090] |
Photoinduced Sequence-Controlled Copper-Mediated Polymerization: Synthesis of Decablock Copolymers |
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Y. Chuang, A. Ethirajan T. Junkers, ACS Macro Lett., 2014, 3, 732-737.
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| [089] |
Thermal detection of histamine with a graphene oxide based molecularly imprinted polymer platform prepared by reversible addition–fragmentation chain transfer polymerization |
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M. Peeters, S. Kobben, K.L. Jimenez-Monroy, L. Modesto, M. Kraus, T. Vandenryt, A. Gaulke, B. van Grinsven, S. Ingebrandt, T. Junkers, P. Wagner, Sens. Actuators B: Chem. 2014, 203, 527-535.
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| [088] |
Synthesis of Degradable Poly(Methyl Methacrylate) Star Polymers via RAFT Copolymerization with Cyclic Ketene Acetals |
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S. Kobben, A. Ethirajan, T. Junkers, J. Polym. Sci. Polym. Chem. 2014, 52, 1633-1641. (see Journal Cover Page)
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| [087] |
Cross-linked degradable poly(β-thioester) networks via amine-catalyzed thiol-ene click polymerization |
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J. Vandenbergh, M. Peeters, T. Kretschmer, P. Wagner, T. Junkers, Polymer 2014, 55, 3525–3532.
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| [086] |
Synthesis of PPV-b-PEG block copolymers via CuAAC conjugation |
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I. Cosemans, J. Vandenbergh, L. Lutsen, D. Vanderzande, T. Junkers, Eur. Polym. J. 2014, 55, 114-122.
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| [085] |
Photo-Induced Copper-Mediated Polymerization of Methyl Acrylate in Continuous Flow Reactors |
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B. Wenn, M. Conradi, A. Demetrio Carreiras, D. Haddleton, T. Junkers, Polym. Chem. 2014, 5, 3053-3060.
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| [084] |
Polymer end group modifications and polymer conjugations via click chemistry employing microreactor technology |
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J. Vandenbergh, T. Tura, E. Baeten, T. Junkers, J. Polym. Sci. Polym. Chem. 2014, 52, 1263-1274.
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| [083] |
Nitrone-Mediated Radical Coupling of Polymers Derived from Reverse Iodine-Transfer Polymerization |
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K. Ranieri, J. Vandenbergh, C. Barner-Kowollik, T. Junkers, Macromol. Chem. Phys. 2014, 215, 1991-2000.
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| [082] |
Facile design of biodegradable poly(beta-thioester)s with tunable structure and functionality |
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N. Zaquen, B, Wenn, K. Ranieri, J. Vandenbergh, T. Junkers, J. Polym. Sci. Polym. Chem. 2014, 52, 178-187. (see Journal Cover Page)
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| [081] |
Critically Evaluated Rate Coefficients in Radical Polymerization - 7. Secondary-Radical Propagation Rate Coefficients for Methyl Acrylate in Bulk |
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C. Barner-Kowollik, S. Beuermann, M. Buback, P. Castignolles, B. Charleux, M.L. Coote, R.A. Hutchinson, T. Junkers, I. Lacík, G.T. Russell, M. Stach, A.M. van Herk, Polym. Chem. 2014, 5, 204-212. |
| [080] |
Straightforward Synthesis of Symmetrical Multiblock Copolymers by Simultaneous Block Extension and Radical Coupling Reactions |
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A. Debuigne, C. Detrembleur, C. Jerome, T. Junkers, Macromolecules 2013, 46, 8922-8931.
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| [079] |
Synthesis of Sequence-Controlled Acrylate Oligomers via Consecutive RAFT Single Monomer Insertions |
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J. Vandenbergh, G. Reekmans, P. Adriaensens, T. Junkers, Chem. Commun. 2013, 49, 10358-10360.
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| [078] |
Synthesis of Macromonomers from High-Temperature Activation of NMP-made Polyacrylates |
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J. Vandenbergh, T. Junkers, Macromolecules 2013, 46, 3324-3331.
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| [077] |
Synthesis of well-defined PPV containing block copolymers with precise endgroup control from a dual-initiator strategy |
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I. Cosemans, J. Vandenbergh, L. Lutsen, D. Vanderzande, T. Junkers, Polym. Chem. 2013, 4, 3471-3479.
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| [076] |
Synthesis of MDMO-PPV nanoparticles via in-situ sulfinyl precursor route polymerization in miniemulsion |
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A. Ethirajan, L. D'Olieslaeger, J. Vandenbergh, L. Lutsen, M. D'Olieslaeger, D. Vanderzande, T. Junkers, Macromol. Chem. Phys. 2013, 214, 1859-1864.
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| [075] |
Precision Synthesis of Acrylate Multiblock Copolymers from Consecutive Microreactor RAFT Polymerizations |
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J. Vandenbergh, T. M. Ogawa, T. Junkers, J. Polym. Sci. Polym. Chem. 2013, 51, 2366-2374. (see Journal Cover Page)
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| [074] |
UV-induced functionalization of poly(divinylbenzene) nanoparticles via efficient [2+2] cycloadditions |
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A. Ethirajan, L. Baeten, M. Conradi, K. Ranieri, B. Conings, H.-G. Boyen, T. Junkers, Polym. Chem. 2013, 4, 4010-4016.
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| [073] |
Efficient [2+2] Photocycloadditions under Equimolar Conditions by Employing a Continuous UV-Flow Reactor |
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M. Conradi, T. Junkers, J. Photochem. Photobiol. A 2013, 259, 41-46.
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| [072] |
Anionic PPV Polymerization from the Sulfinyl Precursor Route: Block Copolymer Formation from Sequential Addition of Monomers |
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I. Cosemans, J. Vandenbergh, V. Voet, K. Loos, L. Lutsen, D. Vanderzande, T. Junkers, Polymer 2013, 54, 1298-1304.
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| [071] |
Enhanced Spin Capturing Polymerization of Ethylene |
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C. Dommanget, C. Boisson, B. Charleux, F. D’Agosto, V. Monteil, F. Boisson, T. Junkers, C. Barner-Kowollik, Y. Guillaneuf, D. Gigmes, Macromolecules 2013, 46, 29-36.
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| [070] |
Transfer Reactions in Phenyl Carbamate Ethyl Acrylate Polymerizations |
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F. Bennet, T. Rölle,T. Fäcke, M.-S. Weiser, F.-K. Bruder, C. Barner-Kowollik, T. Junkers, Macromol. Chem. Phys. 2013, 214, 236-245. |
| [069] |
Synthesis of (Bio)-Degradable Poly(ß-thioester)s via Amine Catalyzed Thiol-Ene Click Polymerization |
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J. Vandenbergh, K. Ranieri, T. Junkers, Macromol. Chem. Phys. 2012, 213, 2611-2617.
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| [068] |
Macromonomers from AGET Activation of Poly(n-Butyl Acrylate) Precursors: Radical Transfer Pathways and Midchain Radical Migration |
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J. Vandenbergh, T. Junkers, Macromolecules 2012, 45, 6850-6856.
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| [067] |
SP-PLP-EPR Investigations into the Termination Kinetics of n-Butyl Acrylate Macromonomers |
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J. Barth, M. Buback, C. Barner-Kowollik, T. Junkers, G. T. Russell, J. Polym. Sci. Polym. Chem. 2012, 50, 4740-4748.
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| [066] |
Investigation of the Endgroup Fidelity at High Conversion during Nitroxide-Mediated Acrylate Polymerizations |
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Y. Guillaneuf, D. Gigmes, T. Junkers, Macromolecules 2012, 45, 5371-5378.
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| [065] |
Use of a Continuous-Flow Microreactor for Thiol-Ene Functionalization of RAFT-Derived Poly(Butyl Acrylate) |
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J. Vandenbergh, T. Junkers, Polym. Chem. 2012, 3, 2739-2742.
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| [064] |
Enhanced Spin Capturing Polymerization and Radical Coupling Mediated by Cyclic Nitrones |
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K. Ranieri, M. Conradi, P.-Y. Chavant, V. Blandin, C. Barner-Kowollik, T. Junkers, Aust. J. Chem. 2012, 65, 1110-1116.
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| [063] |
Thioketone-Mediated Polymerization with Dithiobenzoates: Proof for the Existence of Stable Radical Intermediates in RAFT Polymerization |
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T. Junkers, G. Delaittre, R. Chapman, F. Günzler, E. Chernikova, C. Barner-Kowollik, Macromol. Rapid Commun. 2012, 33, 984-990.
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| [062] |
Thermally Responsive Core-shell Microparticles and Cross-Linked Networks Based on Nitrone Chemistry |
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L. Barner, A. S. Quick, A. P. Vogt, V. Winkler, T. Junkers, C. Barner-Kowollik, Polym. Chem. 2012, 3, 2266-2276.
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| [061] |
A Qualitative and Quantitative Post-Mortem Analysis: Studying Free-Radical Initiation Processes via Soft Ionization Mass Spectrometry
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D. Voll, T. Junkers, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2012, 50, 2739-2757.
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| [060] |
Interpolymer radical coupling: a toolbox complementary to controlled radical polymerization |
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A. Debuigne, M. Hurtgen, C. Detrembleur, C. Jérôme, C. Barner-Kowollik, T. Junkers, Prog. Polym. Sci. 2012, 37, 1004-1030.
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| [059] |
Controlled Synthesis of MDMO-PPV and Block Copolymers Made Thereof |
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J. Vandenbergh, I. Cosemans, L. Lutsen, D. Vanderzande, T. Junkers, Polym. Chem. 2012, 3, 1722-1725.
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| [058] |
A Living Polymerization Method for the Synthesis of PPV Materials |
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I. Cosemans, J. Wouters, W. Maes, T. J. Cleij, L. Lutsen, T. Junkers, D. J. M. Vanderzande, Macromol. Rapid Commun. 2012, 33, 242-247.
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| [057] |
Quantifying Photoinitiation Efficiencies in a Multi-Photoinitiated Free Radical Polymerization |
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D. Voll, A. Hufendiek, T. Junkers, C. Barner-Kowollik, Macromol. Rapid Commun. 2012, 33, 47-53.
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| [056] |
Synthesis of poly(p-phenylene vinylene) materials via the precursor routes |
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T. Junkers, J. Vandenbergh, L. Lutsen, P. Adriaensens, D. Vanderzande, Polym. Chem. 2012, 3, 275-285.
|
| [055] |
Synthesis of Amphiphilic Star and H-Shape Polymers via a Combination of Cobalt-Mediated Radical Polymerization and Nitrone-Mediated Radical Coupling Reactions |
| |
C. Detrembleur, A. Debuigne, O. Altintas, M. Conradi, E.H.H. Wong, C. Jérôme, C. Barner-Kowollik, T. Junkers, Polym. Chem. 2012, 3, 135-147. |
| [054] |
Revealing Model Dependencies in “Assessing the RAFT Equilibrium Constant via Model Systems: An EPR Study" |
| |
T. Junkers, C. Barner-Kowollik, M. L. Coote, Macromol. Rapid Commun. 2011, 32, 1891-1898.
|
| [053] |
Photoinduced Conjugation of Aldehyde Functional Polymers with Olefins via [2+2]-Cycloaddition |
| |
M. Conradi, T. Junkers, Macromolecules 2011, 44, 7969-7976. (see Journal Cover Page)
|
| [052] |
Formation of Triblock Copolymers via a Tandem Enhanced Spin Capturing – Nitroxide Mediated Polymerization (ESC-NMP) Reaction Sequence |
| |
T. Junkers, L. Zang, E.H.H. Wong, N. Dingenouts, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2011, 49, 4841-4850. (see Journal Cover Page)
|
| [051] |
Discovery of an anionic polymerization mechanism for high molecular weight PPV derivatives via the sulfinyl precursor route |
| |
I. Cosemans, L. Hontis, D. Van Den Berghe, A. Palmaerts, J. Wouters, W. Maes, T. J. Cleij, L. Lutsen, T. Junkers, D. J. M. Vanderzande, Macromolecules 2011, 44, 7610-7616.
|
| [050] |
A Detailed Investigation of the Free Radical Copolymerization Behavior of n-Butyl Acrylate Macromonomers |
| |
A.M. Zorn, T. Junkers, C. Barner-Kowollik, Macromolecules 2011, 44, 6691-6700.
|
| [049] |
RAFT Kinetics Revisited: Revival of the RAFT Debate |
| |
T. Junkers, J. Polym. Sci. Polym. Chem. 2011, 49, 4154-4163.
|
| [048] |
Quantitative Comparison of the Mesitoyl vs. the Benzoyl Fragment in Photoinitiation: A Question of Origin |
| |
D. Voll, T. Junkers, C. Barner-Kowollik, Macromolecules 2011, 44, 2542-2551.
|
| [047] |
Embedding Multiple Site-Specific Functionalities into Polymer Chains via Nitrone-Mediated Radical Coupling NMRC) Reactions |
| |
E.H.H. Wong, M.H. Stenzel, T. Junkers, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2011, 49, 2118-2126. |
| [046] |
Nitrone-Mediated Radical Coupling (NMRC) Reactions: A New Synthetic Tool Exemplified on Dendrimer Synthesis |
| |
E.H.H. Wong, O. Altintas, M.H. Stenzel, C. Barner-Kowollik, T. Junkers, Chem. Commun. 2011, 47, 5491-5493 (highlighted in Synfacts 2011, 7, 0727)
|
| [045] |
Nitrones in Synthetic Polymer Chemistry |
| |
E.H.H. Wong, T. Junkers, C. Barner-Kowollik, Polym. Chem. 2011, 2, 1008-1017.
|
| [044] |
On the Kinetic and Mechanistic Similarity between RAFT Intermediate and Acrylate Midchain Radicals
|
| |
C. Barner-Kowollik, T. Junkers, J. Polym. Sci. Polym. Chem. 2011, 49, 1293-1297.
|
| [043] |
Clicking Polymers or Just Efficient Linking: What Makes the Difference? |
| |
C. Barner-Kowollik, F.E. Du Prez, P. Espeel, C.J. Hawker, T. Junkers, H. Schlaad, W. Van Camp, Angew. Chem. Int. Ed. 2011, 50, 60-62. (Engl. Version) Angew. Chem. 2011, 123, 61-64 (German translation) |
| [042] |
Determination of Propagation Rate Coefficients for Methyl and 2-Ethylhexyl Acrylate via High Frequency PLP-SEC under Consideration of the Impact of Chain Branching |
| |
T. Junkers, M. Schneider-Baumann, S.P.S. Koo, P. Castignolles, C. Barner-Kowollik, Macromolecules 2010, 43, 10427-10434.
|
| [041] |
Control of Methyl Methacrylate Radical Polymerization via Enhanced Spin Capturing Polymerization (ESCP) |
| |
L. Zang, E.H.H. Wong, C. Barner-Kowollik, T. Junkers, Polymer 2010, 51, 3821-3825.
|
| [040] |
Reducing the Degree of Branching in Polyacrylates via Mid-Chain Radical Patching: A Quantitative Melt-State NMR Study |
| |
M. Gaborieau, S.P.S. Koo, P. Castignolles, T. Junkers, C. Barner-Kowollik, Macromolecules 2010, 51, 5492-5495.
|
| [039] |
Determination of the Propagation Rate Coefficient of Acrylonitrile |
| |
T. Junkers, S.P.S. Koo, C. Barner-Kowollik, Polym. Chem. 2010, 1, 438-441.
|
| [038] |
Detailed Investigation of the Propagation Rate of Urethane Acrylates |
| |
C. Barner-Kowollik, F. Bennet, M. Schneider-Baumann, D. Voll, T. Rölle, T. Fäcke, M.S. Weiser, F.K. Bruder, T. Junkers, Polym. Chem. 2010, 1, 470-479.
|
| [037] |
Spin Capturing with ‘Clickable’ Nitrones: Generation of Mikto-Armed Star Polymers |
| |
E.H.H. Wong, M.H. Stenzel, T. Junkers, C. Barner-Kowollik, Macromolecules 2010, 43, 3785-3793.
|
| [036] |
Spin Capturing with Nitrones: Radical Coupling Reactions with Concurrent Introduction of Midchain Functionality |
| |
E.H.H. Wong, C. Boyer, M.H. Stenzel, C. Barner-Kowollik, T. Junkers, Chem. Commun. 2010, 46, 1959-1961.
|
| [035] |
Limitations of Radical Thiol-ene Reactions for Polymer-Polymer Conjugation |
| |
S.P.S. Koo, M.M. Stamenovic, R.A. Prasath, A.J. Inglis, F.E. Du Prez, C. Barner-Kowollik, W. Van Camp, T. Junkers, J. Polym. Sci. Polym. Chem. 2010, 48, 1699-1713. (see Journal Cover Page)
|
| [034] |
Mark Houwink Parameters for the Universal Calibration of Acrylate, Methacrylate and Vinyl Acetate Polymers Determined by Online Size-Exclusion Chromatography – Mass Spectrometry |
| |
T. Gruendling, T. Junkers, M. Guilhaus, C. Barner-Kowollik, Macromol. Chem. Phys. 2010, 211, 520-528. |
| [033] |
Synthesis of a Macromonomer Library from High-Temperature Acrylate Polymerization |
| |
A.M. Zorn, T. Junkers, C. Barner-Kowollik, Macromol. Rapid Commun. 2009, 30, 2028-2035.
|
| [032] |
Continuous ATRP Synthesis of Block-like Copolymers via Column Reactors: Design and Validation of a Kinetic Model |
| |
B. Dervaux, T. Junkers, C. Barner-Kowollik, F.E. Du Prez, Macromol. React. Eng. 2009, 3, 529-538.
|
| [031] |
Propagation Rate Coefficients of Isobornyl Acrylate, tert-Butyl Acrylate and 1-Ethoxyethyl Acrylate: A High Frequency PLP-SEC Study |
| |
B. Dervaux, T. Junkers, M. Schneider-Baumann, F.E. Du Prez, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2009, 47, 6641-6657.
|
| [030] |
Optimum Reaction Conditions for the Synthesis of Macromonomers via High-Temperature Polymerization of Acrylates |
| |
T. Junkers, C. Barner-Kowollik, Macromol. Theory Simul. 2009, 18, 421-433. (see Article Frontpiece)
|
| [029] |
Formation Efficiency of ABA Blockcopolymers via Enhanced Spin Capturing Polymerization (ESCP): Locating the Alkoxyamine Function |
| |
T. Junkers, E.H.H. Wong, M.H. Stenzel, C. Barner-Kowollik, Macromolecules 2009, 18, 421-433.
|
| [028] |
Free-Radical Propagation and Termination Kinetics of the Butyl Acrylate Dimer Studied by Pulsed Laser Polymerization Techniques |
| |
M. Buback, T. Junkers, M. Müller, Polymer 2009, 50, 3111-3118.
|
| [027] |
Determination of Vinyl Acetate Propagation Rate Coefficients via High Frequency Pulsed Laser Polymerization |
| |
T. Junkers, D. Voll, C. Barner-Kowollik, e-polymers 2009, 076.
|
| [026] |
Quantifying the Efficiency of Photo-Initiation Processes in Methyl Methacrylate Free Radical Polymerization via Electrospray Ionization Mass Spectrometry |
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F. Günzler, E.H.H. Wong, S.P.S. Koo, T. Junkers, C. Barner-Kowollik, Macromolecules 2009, 42, 1488-1493.
|
| [025] |
Studying the Mechanism of Thioketone Mediated Polymerization (TKMP) via Electrospray Ionization Mass Spectrometry |
| |
F. Günzler, T. Junkers, C. Barner-Kowollik, C, J. Polym. Sci. Polym. Chem. 2009, 47, 1864-1876.
|
| [024] |
The Kinetics of Enhanced Spin Capturing Polymerization (ESCP): Influence of the Nitrone Structure |
| |
E.H.H. Wong, M.H. Stenzel, T. Junkers, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2009, 47, 1098-1107.
|
| [023] |
Quantitative Product Spectrum Analysis of Poly(Butyl Acrylate) via Electrospray Ionization Mass Spectrometry |
| |
S.P.S. Koo, T. Junkers, C. Barner-Kowollik, Macromolecules 2009, 42, 62-69. |
| [022] |
Pushing the Limit: Pulsed Laser Polymerization of Butyl Acrylate at 500 hz |
| |
C. Barner-Kowollik, F. Günzler, T. Junkers, Macromolecules 2008, 41, 8971-8973.
|
| [021] |
A Study into the Stability of 3,6-Dihydro-2H-thiopyran Rings: Key Linkages in the RAFT Hetero Diels-Alder Click Concept |
| |
S. Sinnwell, C.V. Synatschke, T. Junkers, M.H. Stenzel, C. Barner-Kowollik, Macromolecules 2008, 41, 7904-7912.
|
| [020] |
The Role of Mid-chain Radicals in Acrylate Free Radical Polymerization: Branching and Scission |
| |
T. Junkers, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2008, 46, 7585-7605. (see Journal Cover Page)
|
| [019] |
Enhanced Spin Capturing polymerization: An Efficient and Versatile protocol for Controlling Molecular Weight Distributions |
| |
E.H.H. Wong, T. Junkers, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2008, 146, 7273-7279.
|
| [018] |
Controlling the Fate of Midchain Radicals in Acrylate Polymerization |
| |
T. Junkers, J. Polym. Sci. Aust. J. Chem. 2008, 61, 646. |
| [017] |
Self-Directed Formation of Uniform Unsaturated Macromolecules from Acrylate Monomers at High Temperatures |
| |
T. Junkers, F. Bennet, S.P.S. Koo, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2008, 46, 3433-3437.
|
| [016] |
Laser Induced Marking of Polymer Chains with Radical Spin Traps |
| |
T. Junkers, E.H.H. Wong, Z. Szablan, T.P. Davis, M.H. Stenzel, C. Barner-Kowollik, Macromol. Rapid. Commun. 2008, 29, 503-510.
|
| [015] |
PLP labelling in ESR spectroscopic Analysis of Secondary and Tertiary Acrylate Propagating Radicals |
| |
M. Buback, P. Hesse, T. Junkers, T. Sergeeva, T. Theis, Macromolecules 2008, 41, 288-291. |
| [014] |
Chain-Length-Dependent Termination in Acrylate Radical Polymerization Studied via Pulsed-Laser-Initiated RAFT Polymerization |
| |
M. Buback, P. Hesse, T. Junkers, T. Theis, P. Vana, P, Aust. J. Chem. 2007, 60, 779-787.
|
| [013] |
Mapping Poly(butyl acrylate) Product Distributions by Mass Spectrometry in a Wide Temperature Range: Suppression of Midchain Radical Side Reactions |
| |
T. Junkers, S.P.S. Koo, M.H. Stenzel, T.P. Davis, C. Barner-Kowollik, Macromolecules 2007, 40, 8906-8912.
|
| [012] |
Mapping Photolysis Product Radical Reactivities via Soft Ionization Mass Spectrometry in Acrylate, Methacrylate and Itaconate Systems |
| |
Z. Szablan, T. Junkers, S.P.S. Koo, T.M. Lovestead, M.H. Stenzel, T.P. Davis, C. Barner-Kowollik, Macromolecules 2007, 40, 6820-6833.
|
| [011] |
Thioketone–Mediated Polymerization of Butyl Acrylate: Controlling Free-Radical Polymerization via a Dormant Radical Species |
| |
T. Junkers, M.H. Stenzel, T.P. Davis, C. Barner-Kowollik, Macromol. Rapid Commun. 2007, 28, 746-753. |
| [010] |
Termination Kinetics of tert-Butyl Methacrylate and of n-Butyl Methacrylate Free-Radical Bulk Homopolymerizations |
| |
M. Buback, T. Junkers, Macromol. Chem. Phys. 2006, 207, 1640-1650.
|
| [009] |
Determination of Addition and Fragmentation Rate Coefficients in RAFT Polymerization via Time-Resolved ESR Spectroscopy after Laser Pulse Initiation |
| |
M. Buback, P. Hesse, T. Junkers, P. Vana, Macromol. Rapid Commun. 2006, 27, 182-187.
|
| [008] |
Mechanism of Poly(Methyl Methacrylate) Film Growth During Pulse Laser Deposition |
| |
E. Süske, T. Scharf, T. Junkers, M. Buback, H.U. Krebs, J. Appl. Phys. 2006, 10, No. 014906.
|
| [007] |
Free-Radical Polymerization Kinetics of 2-Acrylamido-2-MethylpropaneSulfonic Acid in Aqueous Solution |
| |
S. Beuermann, M. Buback, P. Hesse, T. Junkers, I. Lacík, Macromolecules 2006, 39, 509-516. |
| [006] |
Chain Length Dependent Termination in Butyl Acrylate Free–Radical Polymerization Studied via Stationary and Pulsed Laser Initiated RAFT Polymerization |
| |
T. Junkers, A. Theis, M. Buback, T.P. Davis, M.H. Stenzel, P. Vana, C. Barner-Kowollik, Macromolecules 2005, 38, 9497-9508.
|
| [005] |
Laser Single Pulse Initiated RAFT Polymerization for Assessing Chain-Length Dependent Radical Termination Kinetics |
| |
M. Buback, T. Junkers, P. Vana, Macromol. Rapid Commun. 2005, 26, 796-802.
|
| [004] |
PLP-ESR Monitoring of Mid-chain Radicals in n-Butyl Acrylate Polymerization |
| |
R.X.E. Willemse, A.M. van Herk, E. Panchenko, T. Junkers, M. Buback, Macromolecules 2005, 38, 5098-5103.
|
| [003] |
Tuning of Cross-Linking and Mechanical Properties of Laser Deposited Poly(Methyl Methacrylate) Films |
| |
E. Süske, T. Scharf, H.U. Krebs, E. Panchenko, T. Junkers, M. Egorov, M. Buback, H. Kijewski, H., J. Appl. Phys. 2005, 97, No. 063501.
|
| [002] |
Termination Kinetics of di-n-Butyl Itaconate Free-Radical Polymerization Studied via the SP-PLR-ESR Technique |
| |
M. Buback, M. Egorov, T. Junkers, E. Panchenko, Macromol. Chem. Phys. 2005, 206, 333-341.(see Journal Cover Page) |
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