Publications
Cover Pages
In press / submitted
[226] Autonomous Size-Targeting for Block Copolymer Nanoparticles
O. Weismantel, L. J. Weerarathna, T. Junkers, submitted.[225] Comprehensive Screening of Conditions for Block Copolymer Nanoaggregate Formation via Automated DLS
L. J. Weerarathna, O. Weismantel, T. Junkers, submitted.[224] Depolymerisation of Poly(Lactide) Under Continuous Flow Conditions
S. Ellis, A. Buchard, T. Junkers, submitted.[223] Temperature Effects in Conventional and RAFT Photopolymerization
T. Nwoko, B. Zhang, T. Vargo, T. Junkers, D. Konkolewicz, submitted.[222] Accelerated Continuous Flow Depolymerization of Poly (Methyl Methacrylate)
K. S. C. Jäger, G. Dev, P.J. Voorter, P. Subramanian, A. Kumar, A. Anastasaki, T. Junkers, submitted.[221] Solvent Quality Shape Control in Continuous Flow Block Copolymer Self-Assembly
A.-L. Buckinx, L. J. Weerarathnaa, A. Sokolova, T. Junkers, submitted.2024
[220] Real-Time Determination of Molecular Weight: Use of MaDDOSY (Mass Determination Diffusion Ordered Spectroscopy) to Monitor the Progress of Polymerization Reactions
O. Tolley, W. Pointer, R. Radmall, M. Hall, T. Swift, J. Town, C. Aydogan, T. Junkers, P. Wilson, D. Lester, D. Haddleton, ACS Polym. Au 2024, 4, 311–319.[219] Kinetic investigation of photoiniferter-RAFT polymerization in continuous flow using inline NMR analysis
M. A. Bereś, B. Zhang, T. Junkers, S. Perrier, Polym. Chem. 2024, 15, 3166-3175. doi: 10.1039/D4PY00409D[218] Synthesis of nucleobase functionalised block copolymers towards precision self-assembly
I. Abeysekera, L. Maes, T. Junkers, Polym. Chem. 2024, 15, 2129-2139.[217] Towards universal use of DOSY as a molar mass characterization tool: Temperature dependence investigations and a software tool to process diffusion coefficients
I. W. F. da Silva, , A. I. McKay, A. Sokolova, T. Junkers, Polym. Chem., 2024, 15, 1303-1309.[216] MaDDOSY (Mass Determination Diffusion Ordered Spectroscopy) using a 80 MHz Bench Top NMR for the Rapid Determination of Polymer and Macromolecular Molecular Weight
O. Tolley, W. Pointer, R. Radmall, M. Hall, V. Beyer, K. Stakem, T. Swift, J. Town, T. Junkers, P. Wilson, D. Lester, D. Haddleton, Macromol. Rapid Commun. 2024, e2300692. doi: 10.1002/marc.202300692.[215] Folding Mass Spectra: How to Deal with the Signal to Noise √N dilemma
T. Junkers, I. Abeysekera, Polym. Chem. 2024, 15, 6-10.[214] Lewis acid catalysed polymerisation of cyclopentenone
D. Dissanayake, A. Draper, Z. Liu, N. Jaunnoo, J. J. Haven, C. Forsyth, A. I. McKay, T. Junkers, D. Vidović, Chem. Sci. 2024, 15, 639-643.[213] Controlled Radical Depolymerization: Towards Structural Differentiation of Copolymers and Molecular Weight Control
H. S. Wang, K. Parkatzidis, T. Junkers, N. P. Truong, A. Anastasaki, Chem 2024, 10, 388-401. https://doi.org/10.1016/j.chempr.2023.09.0272023
[212] A fast and efficient way of obtaining the average molecular weight of block copolymers via DOSY
P.J. Voorter, M. Wagner, C. Rosenauer, J. Dai, P. Subramanian, A. McKay, N.R. Cameron, J.J. Michels, T. Junkers, Polym. Chem. 2023, 14, 5140-5146. https://doi.org/10.1039/D3PY01075A[211] High Throughput Multidimensional Kinetic Screening in Continuous Flow Reactors
B. Zhang, A. Mathoor, T. Junkers, Angew. Chem. Int. Ed. 2023, 62, e202308838. https://doi.org/10.1002/anie.202308838[210] Process intensification of continuous-flow seATRP by a sonicated multi-reactor setup
S. Zhang, T. Junkers, S. Kuhn, React Eng. Chem. 2023, 8, 2170-2176. https://doi.org/10.1039/D3RE00235G[209] From monomer to micelle: A facile approach in the multi-step synthesis of block copolymers via inline purification
P.J. Vooerter, G. Dev Amini, A.-L. Buckinx, J. Dai, P. Subramanian, A. Kumar, N. R. Cameron, T. Junkers, Chem. Sci. 2023, 14, 8466-8473. https://doi.org/10.1039/D3SC01819A[208] Narrowing Down Chain Length Effects on the Antibacterial Action of Guanylated Oligomers
D. Wyers, T. Jirapanjawat, J.F. Quinn, M. R. Whittaker, C. Greening, T. Junkers, Polym. Chem. 2023, 14, 2126-2134. https://doi.org/10.1039/D3PY00203A[207] Comprehensive High-throughput Screening of Photopolymerization under Light Intensity Variation using Inline NMR Monitoring
G. Dev, J. Hooker, J. Van Herck, A. Kumar, T. Junkers, Polym. Chem. 2023, 14, 2708-2716. https://doi.org/10.1039/D3PY00190C[206] A Predictive Machine-Learning Model for Propagation Rate Coefficients in Radical Polymerization
E. Van de Reydt, N. Marom, J. Saunderson, M. Boley, T. Junkers, Polym. Chem. 2023, 14, 1622-1629. https://doi.org/10.1039/D2PY01531E[205] Photoresponsive Emulsion-Templated Porous Materials via Orthogonal Photoclick Chemistry
J.P. Hooker, B. Parker, E. Wright, T. Junkers, N.R. Cameron ACS Appl. Mater. Interfaces 2023, 15, 8, 11141–11149. https://doi.org/10.1021/acsami.2c225462022
[204] Continuous-flow self-supported seATRP using a sonicated microreactor
S. Zhang, T. Junkers, S. Kuhn, Chem. Sci 2022, 13, 12326-12331.[203] Operator-Independent High-Throughput Polymerization Screening Based on Automated Inline NMR and Online SEC
H. Van Herck, I. Abeysekara, A.-L. Buckinx, K. Cai, J. P. Hooker, K. Thakur, E. Van de Reydt, P.J. Voorter, D. Wyers, T. Junkers, Digital Discovery 2022, 1, 519-526.[202] Update and Critical Reanalysis of IUPAC Benchmark Propagation Rate Coefficient Data
S. Beuermann, S. Harrisson, R.A. Hutchinson, T. Junkers, G. Russell, Polym. Chem. 2022, 13, 1891-1900. doi.org/10.1039/D2PY00147K[201] The effects of molecular weight dispersity on block copolymer self-assembly
A.-L. Buckinx, M. Rubens, C. Bakkali-Hassani, N. R. Cameron, A. Sokolova, T. Junkers, Polym. Chem. 2022, 13, 3444-3450.[200] Pulsed Laser Polymerization – Size Exclusion Chromatography Investigations into Backbiting in Ethylhexyl Acrylate Polymerization
G. Quintens, T. Junkers, Polym. Chem. 2022, 13, 2019-2025. 10.1039/D1PY01533H[199] Amphiphilic Conjugated Block Copolymers as NIR-Bioimaging Probes
A.-L. Buckinx, A. Rozario, T. D. M. Bell, J. Michels, T. Junkers, Polym. Chem. 2022,13, 2057-2064. doi.org/10.1039/D2PY00258B[198] Rapid Kinetic Screening via Transient Timesweep Experiments in Continuous Flow Reactors
J. Van Herck, T. Junkers, Chem. Methods 2022, 2, e202100090. DOI: 10.1002/cmtd.202100090[197] One-Pot Multifunctional Polyesters by Continuous Flow Organocatalysed Ring-Opening Polymerisation for Targeted and Tunable Materials Design
C. Bakkali-Hassani, J.P. Hooker, P.-J. Voorter, M. Rubens, N.R. Cameron, T. Junkers, Polym. Chem. 2022, accepted. DOI: 10.1039/D2PY00088A[196] Solvent-Independent Molecular Weight Determination of Polymers Based on a Truly Universal Calibration
P.-J. Voorter, A. McKay, J. Dai, O. Paravagna, N. R. Cameron, T. Junkers, Angew. Chem. Int. Ed. 2022, 134, e202114536. DOI: 10.1002/anie.2021145362021
[195] Amino Acid Acrylamide Mimics: Creation of a consistent monomer library and characterization of their polymerization behaviour
D. Wyers, T. Goris, Y. De Smet, T. Junkers, Polym. Chem. 2021, 12, 5037-5047. doi.org/10.1039/D1PY00735A[194] A machine-readable online database for rate coefficients in radical polymerization
J. Van Herck, S. Harrisson, R. A. Hutchinson, G. T. Russell, T. Junkers, Polym. Chem. 2021, 12, 3688-3692. doi.org/10.1039/D1PY00544H[193] Micelle purification in continuous flow via inline dialysis
L. Verstraete, A.-L. Buckinx, N. Zaquen, T. Junkers, Macromolecules 2021, 54, 8, 3865–3872.[192] The Block Copolymer Shuffle in Size Exclusion Chromatography: The Intrinsic Problem with Using Elugrams to Determine Chain Extension Success
K. Philipps, T. Junkers, J. Michels, Polym. Chem. 2021, 12, 2522-2531.[191] Concurrent control over sequence and dispersity in multiblock copolymers
M. N. Antonopoulou,, R. Whitfield, N.P. Truong, D. Wyers, S. Harrisson, T. Junkers, A. Anastasaki, Nat. Chem. 2021. DOI: 10.1038/s41557-021-00818-8[190] Direct Synthesis of Light-Emitting Triblock Copolymers from RAFT Polymerization
A. H. Ribeiro, J. Haven, A.-L.. Buckinx, M. Beuchel, K. Philipps, T. Junkers, J. J. Michels, Polym. Chem. 2021, 12, 216-225.2020
[189] Tunable Thermoresponsive β-cyclodextrin-based Star Polymers
J. Vrijsen, E. Van de Reydt, T. Junkers, J. Polym. Sci. 2020, 58, 3402-3410.[188] Flash-Synthesis of Low Dispersity PPV via Anionic Polymerization in Continuous Flow Reactors
K. Verstraete, N. Zaquen, T. Junkers, Polym. Chem. 2020, 11, 7094-7103.[187] Simple and secure data encryption via molecular weight distribution fingerprints
J. H. Vrijsen, M. Rubens, T. Junkers, Polym. Chem. 2020, 11, 6463-647 .[186] Polymers in the Blender
T. Junkers, Macromol. Chem. Phys. 2020, 221, 2000234. DOI: 10.1002/macp.202000234[185] Designing Molecular Weight Distributions of Arbitrary Shape with Selectable Average Molecular Weight and Dispersity
T. Junkers, J.H. Vrijsen, Eur. Polym. J. 2020, 134, 109834. DOI: 10.1016/j.eurpolymj.2020.109834[184] PEGylating poly(p-phenylene vinylene)-based bioimaging nanoprobes
M. Peters, D. Desta, S. Seneca, G. Reekmans, P. Adriaensens, J.-P. Noben, N. Hellings, T. Junkers, A. Ethirajan, J. Colloid Interface Sci. 2020, 581, 566-575. DOI: 10.1016/j.jcis.2020.07.145[183] Room Temperature Synthesis of Block Copolymer Nano-Objects with Different Morphologies via Ultrasound Initiated RAFT Polymerization-Induced Self-Assembly (Sono-RAFT-PISA)
J. Wan, B. Fan, Y. Liu, T. Hsia, K. Qin, T. Junkers, B. M. Teo, S. Thang, Polym. Chem. 2020, 11, 3564-3572. DOI: 10.1039/D0PY00461H[182] Online Tracing of Molecular Weight Evolution during Radical Polymerization via high-resolution FlowNMR spectroscopy
J. H. Vrijsen, I. A. Thomlinson, M. E. Levere, C. L. Lyall, M. G. Davidson, U. Hintermair, T. Junkers, Polym. Chem. 2020, 11, 3546 - 3550. DOI: 10.1039/D0PY00475H[181] Accelerated Polypeptide Synthesis via N-carboxyanhydride Ring Opening Polymerization in Continuous Flow
J. H. Vrijsen, Alicia R. Mazo, T. Junkers, G. G. Qiao, Macromol. Rapid Commun. 2020, 41, 2000071. DOI: 10.1002/marc.202000071[180] Tailoring Polymer Dispersity by Controlled Radical Polymerization: A Versatile Approach
R. Whitfield, K. Parkatzidis, N. Truong , T. Junkers, A. Anastasaki, Chem 2020, 6, 1340-1352. DOI: 10.1016/j.chempr.2020.04.020[179] Telescoped Continuous Flow Synthesis of Acrylamides
J. Salaklang, E. Mertens, V. Maes, R. Dams, W. Dermaut, T. Junkers, J. Flow Chem. 2020, 10, in press.[178] Polymer Synthesis in Continuous Flow Reactors
N. Zaquen, M. Rubens, N. Corrigan, J. Xu, P.B. Zetterlund, C. Boyer, T. Junkers, Prog. Polym. Sci. 2020, 107, 101256. DOI: 10.1016/j.progpolymsci.2020.101256[177] Photo-Induced Copper-Mediated Acrylate Polymerization towards Graphene Oxide and Reduced Graphene Oxide Modification
S. Railian, J. J. Haven, L. Maes, D. De Sloovere, V. Trouillet, A. Welle, A. Hardy, M. van Bael, W. Deferme, T. Junkers, Eur. Polym. J. 2020, 134, 109810. DOI: 10.1016/j.eurpolymj.2020.109810[176] Muconic acid isomers as platform chemicals and monomers in the biobased economy
I. Khalil, G. Quintens, T. Junkers, M. Dusselier, Green Chem. 2020, 22, 1517-1541. DOI: 10.1039/C9GC04161C[175] Sequence-defined nucleobase containing oligomers via reversible addition-fragmentation chain transfer polymerization
L. Maes, D. M. Roquero, L.M. Pitet, P. Adriaensens, T. Junkers, Polym. Chem. 2020, 11, 2027-2033. DOI: 10.1039/C9PY01853K2019
[174] Elucidation of the properties of discrete oligo(meth)acrylates
J. J. Haven, J. De Neve, A. Castro-Villavicencio, T. Junkers, Polym. Chem. 2019, 10, 6540-6544. DOI: 10.1039/C9PY01494B[173] Automated Polymer Synthesis Platform for Integrated Conversion-Targeting Based on Inline Benchtop NMR
M. Rubens, Joren Van Herck, T. Junkers, ACS Macro Lett. 2019, 8, 1437–1441. DOI: 10.1021/acsmacrolett.9b00767[172] Muconic acid esters as bio-based acrylate mimics
G. Quintens, J.H. Vrijsen, P. Adriaensens, D. Vanderzande, T. Junkers, Polym. Chem. 2019, 10, 5555-5563. DOI: 10.1039/C9PY01313J[171] Comprehensive control over molecular weight distributions through automated polymerizations
M. Rubens, T. Junkers, Polym. Chem. 2019, 10, 6315-6323. DOI: 10.1039/C9PY01013K[170] A predictive framework for mixing of low dispersity polymer samples to design custom molecular weight distributions
M. Rubens, T. Junkers, Polym. Chem. 2019, 10, 5721-5725. DOI: 10.1039/C9PY01012B[169] Deconstructing oligomer distributions: Discrete species and artificial distributions
J. De Neve, J.J. Haven, S. Harrisson, T. Junkers, Angew. Chem. Int. Ed. 2019, 131, 14007-14011. DOI: 10.1002/ange.201906842[168] Kinetic Control of Aggregation Shape in Block Copolymer Self‐Assembly
A.-L. Buckinx, K. Verstraete, E. Baeten, R. Tabor, A. Sokolova, N. Zaquen, T. Junkers, Angew. Chem. Int. Ed. 2019, 131, 13799-13802. DOI: 10.1002/anie.201907371[167] Exploring the Photochemical Reactivity of Multifunctional Photocaged Dienes in Continuous Flow
N. Zaquen, J. J. Haven, M. Rubens, O. Altintas, P. Bohlander, J. Offenloch, C. Barner-Kowollik, T. Junkers, ChemPhotoChem 2019, 3, 1146-1152. DOI: 10.1002/cptc.201900142[166] Particle Size Control in Miniemulsion Polymerization via Membrane Emulsification
N. Nauman, N. Zaquen, T. Junkers, C. Boyer, P.B. Zetterlund, Macromolecules 2019, 52, 4492–4499. DOI: 10.1021/acs.macromol.9b00447[165] Influence of dielectric layer thickness and roughness on topographic effects in magnetic force microscopy
A. Krivcov, J. Ehrler, M. Fuhrmann, T. Junkers, H. Möbius, Beilstein J. Nanotechnol. 2019, 10, 1056-1064. DOI: 10.3762/bjnano.10.106[164] Scalable Aqueous RAFT Photo Polymerization-Induced Self-Assembly of Acrylamides for Direct Synthesis of Polymer Nanoparticles for Potential Drug Delivery Applications
N. Zaquen, H. Zhu, A.Kadir, T. Junkers, P.B. Zetterlund, C. Boyer, ACS Appl. Polym. Mat. 2019, 1, 1251–1256. DOI: 10.1021/acsapm.9b00280[163] Photoiniferter surface grafting of poly(methyl acrylate) using xanthates
G. Ramakers, M. Rubens, A. Krivcov, H. Möbius, V. Trouillet, A. Welle, T. Junkers, J. Polym. Sci. Polym. Chem. 2019, accepted, DOI: 10.1002/pola.29405[162] Alcohol-based PISA in Batch and Flow: Exploring the Role of Photoinitiators
N. Zaquen, W. Azizi, J. Yeow, R. P. Kuchel, T. Junkers, C. Boyer, P.B. Zetterlund, Polym. Chem 2019, 57, 2002-2007. DOI: 10.1039/C9PY00166B[161] Continuous Flow Synthesis of Core Cross-Linked Star Polymers via Photo-Induced Copper Mediated Polymerization
J. H. Vrijsen, C. O. Meideiros, J. Gruber, T. Junkers, Polym. Chem 2019, 10, 1591-15982. DOI: 10.1039/C9PY00134D[160] Scalable Synthesis of Sequence-Defined Oligomers via Photoflow Chemistry
M. Van de Walle, K. De Bruycker, T. Junkers, J. P. Blinco, C. Barner-Kowollik, ChemPhotoChem 2019, 3, 225-228. DOI: 10.1002/cptc.201900031.[159] Learning from Peptides to Access Functional Precision Polymer Sequences
E. Maron, J. H. Swisher, J. J. Haven, T. Y. Meier, T. Junkers, H. G. Boerner, Angew. Chem. Int. Ed. 2019, 58, 10747-10751. DOI: 10.1002/anie.201902217[158] Quasi-Monodisperse Polymer Libraries via Flash Column Chromatography: Correlating Dispersity with Glass Transition
J. J. Haven, T. Junkers, Polym. Chem 2019, 10, 679-682. DOI: 10.1039/C8PY01603H[157] Magnetic Force Microscopy of in a Polymer Matrix Embedded Single Magnetic Nanoparticles
A. Krivcov, J. Schneider, T. Junkers, H. Möbius, Phys. Stat Sol. 2019, 216, 1800753. DOI: 10.1002/pssa.201800753[156] Laser-grafted Molecularly Imprinted Polymers for the Detection of Histamine From Organocatalyzed Atom Transfer Radical Polymerization
G. Ramakers, G. Wackers, V. Trouillet, A. Welle, P. Wagner, T. Junkers , Macromolecules 2019, 52, 2304-2313 DOI: 10.1021/acs.macromol.8b02339[155] Rapid Oxygen Tolerant Aqueous RAFT Photopolymerization in Continuous Flow Reactors
N. Zaquen, A.Kadir, A. Iasa, N. Corrigan, T. Junkers, P. B. Zetterlund, C. Boyer, Macromolecules 2019, 52, 1609-1619 DOI: 10.1021/acs.macromol.8b02628[154] Synthesis of functional polymer particles from Morita-Baylis-Hillman polymerization
G. Ramakers, M. Gagliardi, C. D’Incal, D. Molin, T. Junkers Macromol. Rapid Commun. 2019, 39, 1800678. DOI: .10.1002/marc.201800678[153] Mapping Dithiobenzoate-Mediated RAFT Polymerization Products via Online Microreactor/Mass Spectrometry Monitoring
J. J. Haven, T. Junkers, polymers 2019, 10, 1228. DOI: .10.3390/polym10111228[152] Precise polymer synthesis via autonomous self-optimizing flow reactors
M. Rubens, J.H. Vrijsen, J. Laun, T. Junkers, Angew. Chem. Int. Ed. 2019, 58, 3183-3187, DOI: 10.1002/anie.2018103842018
[151] Ultrafast PhotoRAFT Block Copolymerization of Isoprene and Styrene Facilitated Through Continuous Flow Operation
F. Lauterbach, M. Rubens, V. Abetz, T. Junkers, Angew. Chem. Int. Ed. 2018, 57, 14260-14264 . DOI: 10.1002/anie.201809759[150] Reactor Automation in Continuous Flow Polymerisation: On-Demand Delivery of Precision Polymer Materials
J. J. Haven, T. Junkers, Chemistry Today, 2018, 36(5), 42-44. DOI: xxxxxxxxxxx[149] Sequence-Definition from Controlled Polymerization: The Next Generation of Materials
J. De Neve, J. Haven, L. Maes, T. Junkers, Polym. Chem. 2018, 9, 4692-4705. DOI: 10.1039/C8PY01190G[148] Electrostatic and magnetic forces in magnetic force microscopy: towards single superparamagnetic nanoparticle resolution
A. Krivkov, T. Junkers, H. Moebius, J. Phys. Comm, 2018, 2(7), 075019. DOI: 10.1088/2399-6528/aad3a4[147] Micro-Patterned Molecularly Imprinted Polymer Structures on Functionalized Diamond-Coated Substrates for Testosterone Detection
E. Kellens, H. Bove, T. Vandenryt, J. Dekens, j. Lambrichts, S. Drijkoningen, J. D'Haen, W. De Ceuninck, R. Thoelen, T. Junkers, K. Haenen, A. Ethirajan, Biosens. Bioelectron. 2018, 58-65. DOI: 10.1016/j.bios.2018.07.032[146] Visible Light-Mediated Polymerization-Induced Self-Assembly Using Continuous Flow Reactors.
Zaquen, N., Yeow, J., Junkers, T., Boyer, C., & Zetterlund, P. B.. Macromolecules 2018, 51, 5165-5172. DOI: 10.1021/acs.macromol.8b00887[145] Size-Dependent Properties of Functional PPV-based Conjugated Polymer Nanoparticles for Bioimaging.
Peters, M., Seneca, S., Hellings, N., Junkers, T., & Ethirajan, A. Colloids and Surfaces B: Biointerfaces 2018, 169, 494-501. DOI: 10.1016/j.colsurfb.2018.05.055.[144] Reversible Surface Engineering via Nitrone-Mediated Radical Coupling.
J. Laun, W. Marchal, V. Troulliet, A. Welle, A. Hardy, M.K. van Bael, C. Barner-Kowollik, T. Junkers, Langmuir 2018, 34, 3244-3255. DOI: 10.1021/acs.langmuir.7b03167[143] 2D laser lithography on silicon substrates via photoinduced copper-mediated radical polymerization.
J. Laun, Y. De Smet, E. Van de Reydt, A. Krivcov, V. Trouillet, A. Welle, H. Moebius, C. Barner-Kowollik, T. Junkers, Chem. Commun. 2018, 54, 751-754. DOI: 10.1039/c7cc08444g[142] Direct synthesis of acrylate monomers in heterogeneous continuous flow processes
J. Salaklang, V. Maes, M. Conradi, R. Dams, T. Junkers, React. Chem. Eng. 2018, 2, 41-47. DOI: 10.1039/C7RE00120G[141] Precise Macromolecular Engineering via Continuous-Flow Synthesis Techniques
T. Junkers, J. Flow. Chem, 2018, 7, 106-110. DOI: 10.1556/1846.2017.000302017
[140] Photo-induced ring-closure via a looped flow reactor
E. Baeten, M. Rubens, K. N. R. Wuest, C. Barner-Kowollik, T. Junkers, React. Chem. Eng. 2017, 2, 826-829. DOI: 10.1039/C7RE00124J[139] Visible light-induced iniferter polymerization of methacrylates enhanced by continuous flow
M. Rubens, P. Latsrisaeng, T. Junkers, Polym. Chem. 2017, 8, 6496-6505. (see Journal Cover Page). DOI: 10.1039/C7PY01157A[138] Organocatalyzed Photo-Atom Transfer Radical Polymerization of Methacrylic Acid in Continuous Flow and Surface Grafting
G. Ramakers, A. Krivcov, V. Trouillet, A. Welle, H. Möbius, T. Junkers, Macromol. Rapid Commun. 2017, 38, 1700423. DOI: 10.1002/marc.201700423[137] Online Monitoring of Polymerizations: Current Status
J. Haven, T. Junkers, Eur. J. Org. Chem, 2017, 6474-6482. DOI: 10.1002/ejoc.201700851[136] RAFT Multiblock Reactor Telescoping: From Monomers to Tetrablock Copolymers in a Continuous Multistage Reactor Cascade
E. Baeten, J.J. Haven, T. Junkers, Polym. Chem. 2017, 8, 3815-3824. DOI: 10.1039/C7PY00585G[135] Versatile Approach for the Synthesis of Sequence-Defined Monodisperse 18– and 20-mer Oligoacrylates
J. J. Haven, J. A. De Neve, T. Junkers, ACS Macro Lett. 2017, 6, 743–747. DOI: 10.1021/acsmacrolett.7b00430[134] The Kinetics of n-Butyl Acrylate Radical Polymerization Revealed in a Single Experiment by Real Time On-line Mass Spectrometry Monitoring
J. J. Haven, N. Zaquen, M. Rubens, T. Junkers, Macromol. React. 2017, 1700016.(see Journal Cover Page). DOI: 10.1002/mren.201700016[133] Kinetic Monte Carlo Generation of Complete Electron Spray Ionization Mass Spectra for Acrylate Macromonomer Synthesis
P. H. M. Van Steenberge, J. Vandenbergh, M-F. Reyniers, T. Junkers, D.R. D'Hooge, G. B. Marin, Macromolecules 2017, 50, 2625-2636. DOI: 10.1021/acs.macromol.7b00333[132] Facile photo-flow synthesis of branched poly(butyl acrylate)s
O. Eckardt, B. Wenn, P. Biehl, T. Junkers, F. H. Schacher, React. Chem. Eng. 2017, 2, 479-486. DOI: 10.1039/C7RE00013H[131] High-Throughput Polymer Screening in Microreactors: Boosting the Passerini Three Component Reaction
J. J. Haven, E. Baeten, J. Claes, J. Vandenbergh and T. Junkers, Polym. Chem 2017, 8, 2972-2978. DOI: 10.1039/C7PY00360A[130] Precision Polymer Design in Microstructured Flow Reactors: Improved Control and First Upscale at Once
T. Junkers, Macromol. Chem. Phys 2017, 218, 1600421. DOI: 10.1002/macp.201600421[129] Critically evaluated rate coefficients in radical polymerization - 8. Propagation rate coefficients for vinyl acetate in bulk
C. Barner-Kowollik, S. Beuermann, M. Buback, R.A. Hutchinson, T. Junkers, H. Kattner, B. Manders, A.N. Nikitin, G.T. Russell, A.M. van Herk, Macromol. Chem. Phys 2017, 218, 1600357. DOI: 10.1002/macp.2016003572016
[128] Continuous Microflow PhotoRAFT Polymerization
B. Wenn, T. Junkers, Macromolecules 2016, 49, 6888-6895. DOI: 10.1021/acs.macromol.6b01534[127] Advanced Polymer Flow Synthesis
T. Junkers, R. Hoogenboom, Eur. Polym. J. 2016, 80, 175-176. DOI: 10.1016/j.eurpolymj.2016.05.006[126] Photo-Induced Copper-Mediated Acrylate Polymerization in Continuous Flow Reactors
S. Railian, B. Wenn, T. Junkers, J. Flow Chem. 2016, 6, 260-267. DOI: 10.1556/1846.2016.00018[125] PPV Based Conjugated Polymer Nanoparticles as a Versatile Bioimaging Probe: A Closer Look at the Inherent Optical Properties and Nanoparticle-Cell Interactions
M. Peters, N. Zaquen, L. D'Olieslaeger, H. Bové, D. Vanderzande, N. Hellings, T. Junkers, A. Ethirajan, Biomacromolecules 2016,17 (8), 2562-2571. (see Journal Cover Page). DOI: 10.1021/acs.biomac.6b00574[124] Non-crosslinked Profluorescent PPV-based Micellar Systems as a Versatile Theranostic Probe
N. Zaquen, H. Lu, T. Chang, R. Mamdooh, L. Lutsen, D. Vanderzande, M. Stenzel, T. Junkers, Biomacromolecules 2016, 17, 4068-4094. DOI: 10.1021/acs.biomac.6b01653[123] Modifiable Poly(p-Phenylene Vinylene) Copolymers Towards Functional Conjugated Materials
N. Zaquen, K. Verstraete, L. Lutsen, D. Vanderzande, T. Junkers, Polym. Chem. 2016, 7, 4771-4781. DOI: 10.1039/C6PY00688D[122] Photomediated Controlled Radical Polymerization
X. Pan, M. A. Tasdelen, J. Laun, T. Junkers, Y. Yagci, K. Matyjaszewski, Prog. Polym. Sci. 2016, 62, 73-125. DOI: 10.1016/j.progpolymsci.2016.06.005[121] Efficient Multiblock Starpolymer Synthesis from Photo-Induced Copper-Mediated Polymerization with up to 21 Arms
B. Wenn, A. Martens, Y. Chuang, J. Gruber, T. Junkers, Polym. Chem. 2016, 7, 2720-2727. DOI: 10.1039/C6PY00175K[120] Acid-Induced Room Temperature RAFT Polymerization: Synthesis and Mechanistic Insights
J. Vandenbergh, B. Schweitzer-Chaput, M. Klussmann, T. Junkers, Macromolecules, 49, 4124-4135. DOI: 10.1021/acs.macromol.6b00192[119] Anionic Flow Polymerizations Towards Functional Polyphosphoesters in Microreactors: Polymerization and UV-modification
E. Baeten, S. Vanslambrouck, C. Jerome, P. Lecomte, T. Junkers, Eur. Polym. J., 2016, 80, 208-218. DOI: 10.1016/j.eurpolymj.2016.02.012[118] Kilohertz Pulsed-Laser-Polymerization: Simultaneous Determination of Backbiting, Secondary and Tertiary Radical Propagation Rate Coefficients for tert-Butyl Acrylate
B. Wenn, T. Junkers, Macromol. Rapid Commun. 2016, 37, 781-787. DOI: 10.1002/marc.201600011[117] Controlled/Living Polymerization Towards Functional Poly(p-phenylene vinylene) Materials
N. Zaquen, L. Lutsen, D. Vanderzande, T. Junkers, Polym. Chem. 2016, 7, 1355-1367. DOI: 10.1039/C5PY01987G[116] Improved molecular imprinting based on colloidal particles made from miniemulsion: a case study on testosterone and its structural analogues
E. Kellens, H. Bové, M. Conradi, L. D’Olieslaeger, P. Wagner, K. Landfester, T. Junkers, A. Ethirajan, Macromolecules 2016, 49, 2559-2567. DOI: 10.1021/acs.macromol.6b00130[115] Continuous Photoflow Synthesis of Precision Polymers
T. Junkers, B. Wenn, React. Chem. Eng. 2016, 1, 60-64. DOI: 10.1039/C5RE00042D[114] Determining Free-Radical Propagation Rate Coefficients with High Frequency Lasers: Current Status and Future Perspectives
K. B. Kockler, A. P. Haehnel, T. Junkers, C. Barner-Kowollik, Macromol. Rapid Commun. 2016, 37, 123-134. (see Journal Cover Page). DOI: 10.1002/marc.201500503[113] UV-induced [2+2] grafting-to reactions for polymer modification of cellulose
M. Conradi, G. Ramakers, T. Junkers, Macromol. Rapid Commun. 2016, 37, 174-180. DOI: 10.1002/marc.2015004842015
[112] Improved Mechanistic Insights into Radical Sulfinyl Precursor MDMO-PPV Synthesis by Combining Microflow Technology and Computer Simulations
N. Zaquen, P. H.M. Van Steenberge, D. R. D’hooge, M.-F. Reyniers, G. B. Marin, J. Vandenbergh, L. Lutsen, D. J. M. Vanderzande, T. Junkers, Macromolecules 2015, 48, 894-8306. DOI: 10.1021/acs.macromol.5b01884[111] Solvent Effects on kp in Organic Media? – Statement to the Response
A. P. Haehnel, B. Wenn, K. Kockler, T. Bantle, A. M. Misske, F. Fleischhaker, T. Junkers, C. Barner-Kowollik, Macromol. Rapid Commun. 2015, 36, 1984-1986. DOI: 10.1002/marc.201500416[110] Interfacial thiol-isocyanate reactions for functional nanocarriers: A facile route towards tunable morphologies and hydrophilic payload encapsulation
S. Kuypers, S. K. Pramanika, L. D'Olieslaeger, G. Reekmans, M. Peters, J. D'Haen, D. Vanderzande, T. Junkers, P. Adriaensens, A. Ethirajan, Chem. Commun. 2015, 51, 15858-15861. DOI: 10.1039/C5CC05258K[109] Improved Livingness and Control over Branching in RAFT Polymerization of Acrylates: Could Microflow Synthesis Make the Difference?
P. Derboven, P. H. M. Van Steenberge, J. Vandenbergh, M.-F. Reyniers, T. Junkers, D. R. D’hooge, G. B. Marin, Macromol. Rapid Commun. 2015, 36, 2149-2155. (see Journal Cover Page) DOI: 10.1002/marc.201500357[108] Synthesis of Degradable Multi-Segmented Polymers via Michael-Addition Thiol-Ene Step-Growth Polymerization
J. Vandenbergh, G. Ramakers, L. Van Lokeren, G. Van Assche, T. Junkers, RSC Adv. 2015, 5, 81920 - 81932. DOI: 10.1039/C5RA18861J[107] Combustion deposition of MoO3 films: from fundamentals to OPV applications
W. Marchal, C. De Dobbelaere, J. Kesters, G. Bonneux, J. Vandenbergh, H. Damm, T. Junkers, W. Maes, J. D'Haen, M. Van Bael, A. Hardy, RSC Adv. 2015, 5, 91349 - 91362. DOI: 10.1039/C5RA18001E[106] PPV Polymerization via the Gilch Route: Diradical Character of Monomers
J. Ð. Nikolic, S. Wouters, J. Romanova, A. Shimizu, B. Champagne, T. Junkers, D. Vanderzande, D. Van Neck, M. Waroquier, V. Van Speybroeck, S. Catak, Chem. Eur. J. 2015, 21, 19176-19185. DOI: 10.1002/chem.201501900[105] Synthesisof Sequence-Defined Acrylate Oligomers via Photoinduced Copper-Mediated Radical Single Unit Monomer Insertions
J. Vandenbergh, G. Reekmans, P. Adriaensens, T. Junkers, Chem. Sci. 2015, 6, 5753-5761. DOI: 10.1039/C5SC02035B[104] Ligand Switch in Photoinduced Copper-Mediated Polymerization: Synthesis of acrylate-methacrylate block copolymers
Y. Chuang, B. Wenn, S. Gielen, A. Ethirajan T. Junkers, Polym. Chem. 2015, 6, 6488-6497. DOI: 10.1039/C5PY00592B[103] Continuous Poly(2-oxazoline) Triblock Copolymer Synthesis in a Microfluidic Reactor Cascade
E. Baeten, B. Verbraeken, R. Hoogenboom, T. Junkers, Chem. Commun. 2015, 51, 11701-11704. DOI: 10.1039/C5CC04319K[102] Photoinduced acrylate polymerization: Unexpected reduction in chain branching
B. Wenn, G. Reekmans, P. Adriaensens, T. Junkers, Macromol. Rapid Commun. 2015, 36, 1479-1485. (see Journal Cover Page) DOI: 10.1002/marc.201500198[101] Surface Grafting via Photo-induced Copper-mediated Radical Polymerization at Extremely Low Catalyst Concentrations
J. Laun, M. Vorobii, A. de los Santos Pereira, O. Pop-Georgievski, V. Trouillet, A. Welle, C. Barner-Kowollik, C. Rodriguez-Emmenegger, T. Junkers, Macromol. Rapid Commun. 2015, 36, 1681-1686. (see Journal Cover Page) DOI: 10.1002/marc.201500322[100] Improved Photo-Induced Cobalt-Mediated Radical Polymerization in Continuous Flow Photoreactors
A. Kermagoret, B. Wenn, A. Debuigne, C. Jérôme, T. Junkers, C. Detrembleur, Polym. Chem. 2015, 5, 3847-3857. DOI: 10.1039/C5PY00299K[099] Efficiency Assessment on Single Unit Monomer Insertion Reactions for Monomer Sequence Control: Kinetic Simulations and Experimental Observations
J. J. Haven, J. Vandenbergh, R. Kurita, J. Gruber, T. Junkers, Polym. Chem. 2015, 6, 5752-5765. DOI: 10.1039/C5PY00485C[098] Facile Synthesis of Well-Defined MDMO-PPV Containing (Tri)Block - Copolymers via Controlled Radical Polymerization and CuAAC Conjugation
N. Zaquen, J. Vandenbergh, M. Schneider-Baumann, L. Lutsen, D. Vanderzande, T. Junkers, Polymers 2015, 7, 418-452. DOI: 10.3390/polym7030418[097] Continuous Synthesis and Thermal Elimination of Sulfinyl Precursor MDMO-PPV in Consecutive Flow Reactions
N. Zaquen, E. Baeten, J. Vandenbergh, L. Lutsen, D. Vanderzande, T. Junkers, Chem. Eng. Technol. 2015, 38, 1749-1757. DOI: 10.1002/ceat.201400754[096] Watching Polymers Grow: Real Time Monitoring of Polymerizations via an On-line ESI-MS/Microreactor Coupling
J. J. Haven, J. Vandenbergh, T. Junkers, Chem. Commun. 2015, 51, 4611-4614. DOI: 10.1039/C4CC10426A[095] [2+2] Photo-Cycloadditions for Polymer Modification and Surface Decoration
T. Junkers, Eur. Polym. J., 2015, 65, 273-280. DOI: 10.1016/j.eurpolymj.2014.08.0052014
[094] Solvent Effects on kp in Organic Media? - A Systematic PLP-SEC Study
A. P. Haehnel, B. Wenn, K. Kockler, T. Bantle, A. M. Misske, F. Fleischhaker, T. Junkers, C. Barner-Kowollik, Macromol. Rapid Commun., 2014, 35, 2029-2037. DOI: 10.1002/marc.201400479[093] Direct Access to Dithiobenzoate RAFT Agent Fragmentation Rate Coefficients by ESR Spin-Trapping
K. Ranieri, G. Delaittre, C. Barner-Kowollik, T. Junkers, Macromol. Rapid Commun., 2014, 35, 2023-2028. DOI: 10.1002/marc.201400518[092] Fast and Efficient [2 + 2] UV Cycloaddition for Polymer Modification via Flow Synthesis
M. Conradi, T. Junkers, Macromolecules, 2014, 47, 5578-5585. DOI: 10.1021/ma500751j[091] Alpha and Omega: Importance of the Nonliving Chain End in RAFT Multiblock Copolymerization
J. Vandenbergh, T. Junkers, Macromolecules, 2014, 47, 5051-5059. DOI: 10.1021/ma500803k[090] Photoinduced Sequence-Controlled Copper-Mediated Polymerization: Synthesis of Decablock Copolymers
Y. Chuang, A. Ethirajan T. Junkers, ACS Macro Lett., 2014, 3, 732-737. DOI: 10.1021/mz5003867[089] Thermal detection of histamine with a graphene oxide based molecularly imprinted polymer platform prepared by reversible addition–fragmentation chain transfer polymerization
M. Peeters, S. Kobben, K.L. Jimenez-Monroy, L. Modesto, M. Kraus, T. Vandenryt, A. Gaulke, B. van Grinsven, S. Ingebrandt, T. Junkers, P. Wagner, Sens. Actuators B: Chem. 2014, 203, 527-535. DOI: 10.1016/j.snb.2014.07.013[088] Synthesis of Degradable Poly(Methyl Methacrylate) Star Polymers via RAFT Copolymerization with Cyclic Ketene Acetals
S. Kobben, A. Ethirajan, T. Junkers, J. Polym. Sci. Polym. Chem. 2014, 52, 1633-1641. (see Journal Cover Page) DOI: 10.1002/pola.27180[087] Cross-linked degradable poly(β-thioester) networks via amine-catalyzed thiol-ene click polymerization
J. Vandenbergh, M. Peeters, T. Kretschmer, P. Wagner, T. Junkers, Polymer 2014, 55, 3525–3532. DOI: 10.1016/j.polymer.2014.05.043[086] Synthesis of PPV-b-PEG block copolymers via CuAAC conjugation
I. Cosemans, J. Vandenbergh, L. Lutsen, D. Vanderzande, T. Junkers, Eur. Polym. J. 2014, 55, 114-122. DOI: 10.1016/j.eurpolymj.2014.03.016[085] Photo-Induced Copper-Mediated Polymerization of Methyl Acrylate in Continuous Flow Reactors
B. Wenn, M. Conradi, A. Demetrio Carreiras, D. Haddleton, T. Junkers, Polym. Chem. 2014, 5, 3053-3060. DOI: 10.1039/C3PY01762A[084] Polymer end group modifications and polymer conjugations via click chemistry employing microreactor technology
J. Vandenbergh, T. Tura, E. Baeten, T. Junkers, J. Polym. Sci. Polym. Chem. 2014, 52, 1263-1274. DOI: https://doi.org/10.1002/pola.27112[083] Nitrone-Mediated Radical Coupling of Polymers Derived from Reverse Iodine-Transfer Polymerization
K. Ranieri, J. Vandenbergh, C. Barner-Kowollik, T. Junkers, Macromol. Chem. Phys. 2014, 215, 1991-2000. DOI: https://doi.org/10.1002/macp.201300740[082] Facile design of biodegradable poly(beta-thioester)s with tunable structure and functionality
N. Zaquen, B, Wenn, K. Ranieri, J. Vandenbergh, T. Junkers, J. Polym. Sci. Polym. Chem. 2014, 52, 178-187. (see Journal Cover Page) DOI: https://doi.org/10.1002/pola.26986[081] Critically Evaluated Rate Coefficients in Radical Polymerization - 7. Secondary-Radical Propagation Rate Coefficients for Methyl Acrylate in Bulk
C. Barner-Kowollik, S. Beuermann, M. Buback, P. Castignolles, B. Charleux, M.L. Coote, R.A. Hutchinson, T. Junkers, I. Lacík, G.T. Russell, M. Stach, A.M. van Herk, Polym. Chem. 2014, 5, 204-212. DOI: 10.1039/C3PY00774J2013
[080] Straightforward Synthesis of Symmetrical Multiblock Copolymers by Simultaneous Block Extension and Radical Coupling Reactions
A. Debuigne, C. Detrembleur, C. Jerome, T. Junkers, Macromolecules 2013, 46, 8922-8931. DOI: 10.1021/ma401918t[079] Synthesis of Sequence-Controlled Acrylate Oligomers via Consecutive RAFT Single Monomer Insertions
J. Vandenbergh, G. Reekmans, P. Adriaensens, T. Junkers, Chem. Commun. 2013, 49, 10358-10360. DOI: 10.1039/C3CC45994B[078] Synthesis of Macromonomers from High-Temperature Activation of NMP-made Polyacrylates
J. Vandenbergh, T. Junkers, Macromolecules 2013, 46, 3324-3331. DOI: 10.1021/ma400477t[077] Synthesis of well-defined PPV containing block copolymers with precise endgroup control from a dual-initiator strategy
I. Cosemans, J. Vandenbergh, L. Lutsen, D. Vanderzande, T. Junkers, Polym. Chem. 2013, 4, 3471-3479. DOI: 10.1039/C3PY00303E[076] Synthesis of MDMO-PPV nanoparticles via in-situ sulfinyl precursor route polymerization in miniemulsion
A. Ethirajan, L. D'Olieslaeger, J. Vandenbergh, L. Lutsen, M. D'Olieslaeger, D. Vanderzande, T. Junkers, Macromol. Chem. Phys. 2013, 214, 1859-1864. DOI: 10.1002/macp.201300348[075] Precision Synthesis of Acrylate Multiblock Copolymers from Consecutive Microreactor RAFT Polymerizations
J. Vandenbergh, T. M. Ogawa, T. Junkers, J. Polym. Sci. Polym. Chem. 2013, 51, 2366-2374. (see Journal Cover Page) DOI: 10.1002/pola.26593[074] UV-induced functionalization of poly(divinylbenzene) nanoparticles via efficient [2+2] cycloadditions
A. Ethirajan, L. Baeten, M. Conradi, K. Ranieri, B. Conings, H.-G. Boyen, T. Junkers, Polym. Chem. 2013, 4, 4010-4016. DOI: 10.1039/C3PY00427A[073] Efficient [2+2] Photocycloadditions under Equimolar Conditions by Employing a Continuous UV-Flow Reactor
M. Conradi, T. Junkers, J. Photochem. Photobiol. A 2013, 259, 41-46. DOI: 10.1016/j.jphotochem.2013.02.024[072] Anionic PPV Polymerization from the Sulfinyl Precursor Route: Block Copolymer Formation from Sequential Addition of Monomers
I. Cosemans, J. Vandenbergh, V. Voet, K. Loos, L. Lutsen, D. Vanderzande, T. Junkers, Polymer 2013, 54, 1298-1304. DOI: 10.1016/j.polymer.2012.12.070[071] Enhanced Spin Capturing Polymerization of Ethylene
C. Dommanget, C. Boisson, B. Charleux, F. D’Agosto, V. Monteil, F. Boisson, T. Junkers, C. Barner-Kowollik, Y. Guillaneuf, D. Gigmes, Macromolecules 2013, 46, 29-36. DOI: 10.1002/macp.201200285[070] Transfer Reactions in Phenyl Carbamate Ethyl Acrylate Polymerizations
F. Bennet, T. Rölle,T. Fäcke, M.-S. Weiser, F.-K. Bruder, C. Barner-Kowollik, T. Junkers, Macromol. Chem. Phys. 2013, 214, 236-245. DOI: 10.1002/macp.2012002852012
[069] Synthesis of (Bio)-Degradable Poly(ß-thioester)s via Amine Catalyzed Thiol-Ene Click Polymerization
J. Vandenbergh, K. Ranieri, T. Junkers, Macromol. Chem. Phys. 2012, 213, 2611-2617. DOI: 10.1002/macp.201200470[068] Macromonomers from AGET Activation of Poly(n-Butyl Acrylate) Precursors: Radical Transfer Pathways and Midchain Radical Migration
J. Vandenbergh, T. Junkers, Macromolecules 2012, 45, 6850-6856. DOI: 10.1021/ma301233v[067] SP-PLP-EPR Investigations into the Termination Kinetics of n-Butyl Acrylate Macromonomers
J. Barth, M. Buback, C. Barner-Kowollik, T. Junkers, G. T. Russell, J. Polym. Sci. Polym. Chem. 2012, 50, 4740-4748. DOI: 10.1002/pola.26295[066] Investigation of the Endgroup Fidelity at High Conversion during Nitroxide-Mediated Acrylate Polymerizations
Y. Guillaneuf, D. Gigmes, T. Junkers, Macromolecules 2012, 45, 5371-5378. DOI: 10.1021/ma300953b[065] Use of a Continuous-Flow Microreactor for Thiol-Ene Functionalization of RAFT-Derived Poly(Butyl Acrylate)
J. Vandenbergh, T. Junkers, Polym. Chem. 2012, 3, 2739-2742. DOI: 10.1039/C2PY20423A[064] Enhanced Spin Capturing Polymerization and Radical Coupling Mediated by Cyclic Nitrones
K. Ranieri, M. Conradi, P.-Y. Chavant, V. Blandin, C. Barner-Kowollik, T. Junkers, Aust. J. Chem. 2012, 65, 1110-1116. DOI: 10.1071/CH12182[063] Thioketone-Mediated Polymerization with Dithiobenzoates: Proof for the Existence of Stable Radical Intermediates in RAFT Polymerization
T. Junkers, G. Delaittre, R. Chapman, F. Günzler, E. Chernikova, C. Barner-Kowollik, Macromol. Rapid Commun. 2012, 33, 984-990. DOI: 10.1002/marc.201200128[062] Thermally Responsive Core-shell Microparticles and Cross-Linked Networks Based on Nitrone Chemistry
L. Barner, A. S. Quick, A. P. Vogt, V. Winkler, T. Junkers, C. Barner-Kowollik, Polym. Chem. 2012, 3, 2266-2276. DOI: 10.1039/C2PY20272G[061] A Qualitative and Quantitative Post-Mortem Analysis: Studying Free-Radical Initiation Processes via Soft Ionization Mass Spectrometry
D. Voll, T. Junkers, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2012, 50, 2739-2757. DOI: 10.1002/pola.26076[060] Interpolymer radical coupling: a toolbox complementary to controlled radical polymerization
A. Debuigne, M. Hurtgen, C. Detrembleur, C. Jérôme, C. Barner-Kowollik, T. Junkers, Prog. Polym. Sci. 2012, 37, 1004-1030. DOI: 10.1016/j.progpolymsci.2012.01.003[059] Controlled Synthesis of MDMO-PPV and Block Copolymers Made Thereof
J. Vandenbergh, I. Cosemans, L. Lutsen, D. Vanderzande, T. Junkers, Polym. Chem. 2012, 3, 1722-1725. DOI: 10.1039/C2PY00551D[058] A Living Polymerization Method for the Synthesis of PPV Materials
I. Cosemans, J. Wouters, W. Maes, T. J. Cleij, L. Lutsen, T. Junkers, D. J. M. Vanderzande, Macromol. Rapid Commun. 2012, 33, 242-247. DOI: 10.1002/marc.201100758[057] Quantifying Photoinitiation Efficiencies in a Multi-Photoinitiated Free Radical Polymerization
D. Voll, A. Hufendiek, T. Junkers, C. Barner-Kowollik, Macromol. Rapid Commun. 2012, 33, 47-53. DOI: 10.1002/marc.201100655[056] Synthesis of poly(p-phenylene vinylene) materials via the precursor routes
T. Junkers, J. Vandenbergh, L. Lutsen, P. Adriaensens, D. Vanderzande, Polym. Chem. 2012, 3, 275-285. DOI: 10.1039/C1PY00345C[055] Synthesis of Amphiphilic Star and H-Shape Polymers via a Combination of Cobalt-Mediated Radical Polymerization and Nitrone-Mediated Radical Coupling Reactions
C. Detrembleur, A. Debuigne, O. Altintas, M. Conradi, E.H.H. Wong, C. Jérôme, C. Barner-Kowollik, T. Junkers, Polym. Chem. 2012, 3, 135-147. DOI: 10.1039/C1PY00297J2011
[054] Revealing Model Dependencies in “Assessing the RAFT Equilibrium Constant via Model Systems: An EPR Study"
T. Junkers, C. Barner-Kowollik, M. L. Coote, Macromol. Rapid Commun. 2011, 32, 1891-1898. DOI: 10.1002/marc.201100655[053] Photoinduced Conjugation of Aldehyde Functional Polymers with Olefins via [2+2]-Cycloaddition
M. Conradi, T. Junkers, Macromolecules 2011, 44, 7969-7976. (see Journal Cover Page) DOI: 10.1021/ma2017748[052] Formation of Triblock Copolymers via a Tandem Enhanced Spin Capturing – Nitroxide Mediated Polymerization (ESC-NMP) Reaction Sequence
T. Junkers, L. Zang, E.H.H. Wong, N. Dingenouts, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2011, 49, 4841-4850. (see Journal Cover Page) DOI: 10.1002/pola.24970[051] Discovery of an anionic polymerization mechanism for high molecular weight PPV derivatives via the sulfinyl precursor route
I. Cosemans, L. Hontis, D. Van Den Berghe, A. Palmaerts, J. Wouters, W. Maes, T. J. Cleij, L. Lutsen, T. Junkers, D. J. M. Vanderzande, Macromolecules 2011, 44, 7610-7616. DOI: 10.1021/ma201453s[050] A Detailed Investigation of the Free Radical Copolymerization Behavior of n-Butyl Acrylate Macromonomers
A.M. Zorn, T. Junkers, C. Barner-Kowollik, Macromolecules 2011, 44, 6691-6700. DOI: 10.1021/ma201345m[049] A Detailed Investigation of the Free Radical Copolymerization Behavior of n-Butyl Acrylate Macromonomers
A.M. Zorn, T. Junkers, C. Barner-Kowollik, Macromolecules 2011, 44, 6691-6700. DOI: 10.1002/pola.24857[048] Quantitative Comparison of the Mesitoyl vs. the Benzoyl Fragment in Photoinitiation: A Question of Origin
D. Voll, T. Junkers, C. Barner-Kowollik, Macromolecules 2011, 44, 2542-2551. DOI: 10.1021/ma2001977[047] Embedding Multiple Site-Specific Functionalities into Polymer Chains via Nitrone-Mediated Radical Coupling NMRC) Reactions
E.H.H. Wong, M.H. Stenzel, T. Junkers, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2011, 49, 2118-2126. DOI: 10.1002/pola.24639[046] Nitrone-Mediated Radical Coupling (NMRC) Reactions: A New Synthetic Tool Exemplified on Dendrimer Synthesis
E.H.H. Wong, O. Altintas, M.H. Stenzel, C. Barner-Kowollik, T. Junkers, Chem. Commun. 2011, 47, 5491-5493 (highlighted in Synfacts 2011, 7, 0727) DOI: 10.1039/C1CC10322A[045] Nitrones in Synthetic Polymer Chemistry
E.H.H. Wong, T. Junkers, C. Barner-Kowollik, Polym. Chem. 2011, 2, 1008-1017. DOI: 10.1039/C0PY00377H[044] On the Kinetic and Mechanistic Similarity between RAFT Intermediate and Acrylate Midchain Radicals
C. Barner-Kowollik, T. Junkers, J. Polym. Sci. Polym. Chem. 2011, 49, 1293-1297. DOI: 10.1002/pola.24546[043] Clicking Polymers or Just Efficient Linking: What Makes the Difference?
C. Barner-Kowollik, F.E. Du Prez, P. Espeel, C.J. Hawker, T. Junkers, H. Schlaad, W. Van Camp, Angew. Chem. Int. Ed. 2011, 50, 60-62. DOI: 10.1002/anie.2010037072010
[042] Determination of Propagation Rate Coefficients for Methyl and 2-Ethylhexyl Acrylate via High Frequency PLP-SEC under Consideration of the Impact of Chain Branching
T. Junkers, M. Schneider-Baumann, S.P.S. Koo, P. Castignolles, C. Barner-Kowollik, Macromolecules 2010, 43, 10427-10434. DOI: 10.1021/ma102130h[041] Control of Methyl Methacrylate Radical Polymerization via Enhanced Spin Capturing Polymerization (ESCP)
L. Zang, E.H.H. Wong, C. Barner-Kowollik, T. Junkers, Polymer 2010, 51, 3821-3825. DOI: 10.1016/j.polymer.2010.06.040[040] Reducing the Degree of Branching in Polyacrylates via Mid-Chain Radical Patching: A Quantitative Melt-State NMR Study
M. Gaborieau, S.P.S. Koo, P. Castignolles, T. Junkers, C. Barner-Kowollik, Macromolecules 2010, 51, 5492-5495. DOI: 10.1002/pola.24970[039] Determination of the Propagation Rate Coefficient of Acrylonitrile
T. Junkers, S.P.S. Koo, C. Barner-Kowollik, Polym. Chem. 2010, 1, 438-441. DOI: 10.1039/C0PY00019A[038] Detailed Investigation of the Propagation Rate of Urethane Acrylates
C. Barner-Kowollik, F. Bennet, M. Schneider-Baumann, D. Voll, T. Rölle, T. Fäcke, M.S. Weiser, F.K. Bruder, T. Junkers, Polym. Chem. 2010, 1, 470-479. DOI: 10.1039/B9PY00352E[037] Spin Capturing with ‘Clickable’ Nitrones: Generation of Mikto-Armed Star Polymers
A.M. Zorn, T. Junkers, C. Barner-Kowollik, Macromolecules 2011, 44, 6691-6700. DOI: 10.1021/ma100263k[036] Spin Capturing with Nitrones: Radical Coupling Reactions with Concurrent Introduction of Midchain Functionality
E.H.H. Wong, C. Boyer, M.H. Stenzel, C. Barner-Kowollik, T. Junkers, Chem. Commun. 2010, 46, 1959-1961 DOI: 10.1039/B925390D[035] Limitations of Radical Thiol-ene Reactions for Polymer-Polymer Conjugation
S.P.S. Koo, M.M. Stamenovic, R.A. Prasath, A.J. Inglis, F.E. Du Prez, C. Barner-Kowollik, W. Van Camp, T. Junkers, J. Polym. Sci. Polym. Chem. 2010, 48, 1699-1713. (see Journal Cover Page) DOI: 10.1002/pola.23933[034] Mark Houwink Parameters for the Universal Calibration of Acrylate, Methacrylate and Vinyl Acetate Polymers Determined by Online Size-Exclusion Chromatography – Mass Spectrometry
T. Gruendling, T. Junkers, M. Guilhaus, C. Barner-Kowollik, Macromol. Chem. Phys. 2010, 211, 520-528. DOI: 10.1002/macp.2009003232009
[033] Synthesis of a Macromonomer Library from High-Temperature Acrylate Polymerization
A.M. Zorn, T. Junkers, C. Barner-Kowollik, Macromol. Rapid Commun. 2009, 30, 2028-2035. DOI: 10.1002/marc.200900536[032] Continuous ATRP Synthesis of Block-like Copolymers via Column Reactors: Design and Validation of a Kinetic Model
B. Dervaux, T. Junkers, C. Barner-Kowollik, F.E. Du Prez, Macromol. React. Eng. 2009, 3, 529-538 DOI: 10.1002/mren.200900046[031] Propagation Rate Coefficients of Isobornyl Acrylate, tert-Butyl Acrylate and 1-Ethoxyethyl Acrylate: A High Frequency PLP-SEC Study
B. Dervaux, T. Junkers, M. Schneider-Baumann, F.E. Du Prez, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2009, 47, 6641-6657. DOI: 10.1002/pola.23706[030] Optimum Reaction Conditions for the Synthesis of Macromonomers via High-Temperature Polymerization of Acrylates
T. Junkers, C. Barner-Kowollik, Macromol. Theory Simul. 2009, 18, 421-433. (see Journal Cover Page) DOI: 10.1002/mats.200900025[029] Formation Efficiency of ABA Blockcopolymers via Enhanced Spin Capturing Polymerization (ESCP): Locating the Alkoxyamine Function
T. Junkers, E.H.H. Wong, M.H. Stenzel, C. Barner-Kowollik, Macromolecules 2009, 18, 421-433. DOI: 10.1021/ma900356p[028] Free-Radical Propagation and Termination Kinetics of the Butyl Acrylate Dimer Studied by Pulsed Laser Polymerization Techniques
M. Buback, T. Junkers, M. Müller, Polymer 2009, 50, 3111-3118. DOI: 10.1016/j.polymer.2009.04.036[027] Determination of Vinyl Acetate Propagation Rate Coefficients via High Frequency Pulsed Laser Polymerization
T. Junkers, D. Voll, C. Barner-Kowollik, e-polymers 2009, 076. DOI: 10.1515/epoly.2009.9.1.931[026] Quantifying the Efficiency of Photo-Initiation Processes in Methyl Methacrylate Free Radical Polymerization via Electrospray Ionization Mass Spectrometry
F. Günzler, E.H.H. Wong, S.P.S. Koo, T. Junkers, C. Barner-Kowollik, Macromolecules 2009, 42, 1488-1493. DOI: 10.1021/ma802308z[025] Studying the Mechanism of Thioketone Mediated Polymerization (TKMP) via Electrospray Ionization Mass Spectrometry
F. Günzler, T. Junkers, C. Barner-Kowollik, C, J. Polym. Sci. Polym. Chem. 2009, 47, 1864-1876. DOI: 10.1002/pola.23280[024] The Kinetics of Enhanced Spin Capturing Polymerization (ESCP): Influence of the Nitrone Structure
E.H.H. Wong, M.H. Stenzel, T. Junkers, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2009, 47, 1098-1107. DOI: 10.1002/pola.23221[023] Quantitative Product Spectrum Analysis of Poly(Butyl Acrylate) via Electrospray Ionization Mass Spectrometry
S.P.S. Koo, T. Junkers, C. Barner-Kowollik, Macromolecules 2009, 42, 62-69. DOI: 10.1021/ma801196w2008
[022] Pushing the Limit: Pulsed Laser Polymerization of Butyl Acrylate at 500 hz
C. Barner-Kowollik, F. Günzler, T. Junkers, Macromolecules 2008, 41, 8971-8973. DOI: 10.1021/ma8020932[021] A Study into the Stability of 3,6-Dihydro-2H-thiopyran Rings: Key Linkages in the RAFT Hetero Diels-Alder Click Concept
S. Sinnwell, C.V. Synatschke, T. Junkers, M.H. Stenzel, C. Barner-Kowollik, Macromolecules 2008, 41, 7904-7912. DOI: 10.1021/ma8013959[020] The Role of Mid-chain Radicals in Acrylate Free Radical Polymerization: Branching and Scission
T. Junkers, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2008, 46, 7585-7605. (see Journal Cover Page) DOI: 10.1002/pola.23071[019] Enhanced Spin Capturing polymerization: An Efficient and Versatile protocol for Controlling Molecular Weight Distributions
E.H.H. Wong, T. Junkers, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2008, 146, 7273-7279. DOI: 10.1002/pola.23025[018] Controlling the Fate of Midchain Radicals in Acrylate Polymerization
T. Junkers, J. Polym. Sci. Aust. J. Chem. 2008, 61, 646. DOI: 10.1071/CH08198[017] Self-Directed Formation of Uniform Unsaturated Macromolecules from Acrylate Monomers at High Temperatures
T. Junkers, F. Bennet, S.P.S. Koo, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2008, 46, 3433-3437. DOI: 10.1002/pola.22676[016] Laser Induced Marking of Polymer Chains with Radical Spin Traps
T. Junkers, E.H.H. Wong, Z. Szablan, T.P. Davis, M.H. Stenzel, C. Barner-Kowollik, Macromol. Rapid. Commun. 2008, 29, 503-510. DOI: 10.1002/marc.200700820[015] PLP labelling in ESR spectroscopic Analysis of Secondary and Tertiary Acrylate Propagating Radicals
M. Buback, P. Hesse, T. Junkers, T. Sergeeva, T. Theis, Macromolecules 2008, 41, 288-291. DOI: 10.1021/ma702011q2007
[014] Chain-Length-Dependent Termination in Acrylate Radical Polymerization Studied via Pulsed-Laser-Initiated RAFT Polymerization
M. Buback, P. Hesse, T. Junkers, T. Theis, P. Vana, P, Aust. J. Chem. 2007, 60, 779-787. DOI: 10.1071/CH07236[013] Mapping Poly(butyl acrylate) Product Distributions by Mass Spectrometry in a Wide Temperature Range: Suppression of Midchain Radical Side Reactions
T. Junkers, S.P.S. Koo, M.H. Stenzel, T.P. Davis, C. Barner-Kowollik, Macromolecules 2007, 40, 8906-8912. DOI: 10.1021/ma071471+[012] Mapping Photolysis Product Radical Reactivities via Soft Ionization Mass Spectrometry in Acrylate, Methacrylate and Itaconate Systems
Z. Szablan, T. Junkers, S.P.S. Koo, T.M. Lovestead, M.H. Stenzel, T.P. Davis, C. Barner-Kowollik, Macromolecules 2007, 40, 6820-6833. DOI: 10.1021/ma070626a[011] Thioketone–Mediated Polymerization of Butyl Acrylate: Controlling Free-Radical Polymerization via a Dormant Radical Species
T. Junkers, M.H. Stenzel, T.P. Davis, C. Barner-Kowollik, Macromol. Rapid Commun. 2007, 28, 746-753. DOI: 10.1002/marc.2006008852006
[010] Termination Kinetics of tert-Butyl Methacrylate and of n-Butyl Methacrylate Free-Radical Bulk Homopolymerizations
M. Buback, T. Junkers, Macromol. Chem. Phys. 2006, 207, 1640-1650. DOI: 10.1002/macp.200600254[009] Determination of Addition and Fragmentation Rate Coefficients in RAFT Polymerization via Time-Resolved ESR Spectroscopy after Laser Pulse Initiation
M. Buback, P. Hesse, T. Junkers, P. Vana, Macromol. Rapid Commun. 2006, 27, 182-187. DOI: 10.1002/marc.200500716[008] Mechanism of Poly(Methyl Methacrylate) Film Growth During Pulse Laser Deposition
E. Süske, T. Scharf, T. Junkers, M. Buback, H.U. Krebs, J. Appl. Phys. 2006, 10, No. 014906. DOI: 10.1063/1.2209434[007] Free-Radical Polymerization Kinetics of 2-Acrylamido-2-MethylpropaneSulfonic Acid in Aqueous Solution
S. Beuermann, M. Buback, P. Hesse, T. Junkers, I. Lacík, Macromolecules 2006, 39, 509-516. DOI: 10.1021/ma051187n2005
[006] Chain Length Dependent Termination in Butyl Acrylate Free–Radical Polymerization Studied via Stationary and Pulsed Laser Initiated RAFT Polymerization
T. Junkers, A. Theis, M. Buback, T.P. Davis, M.H. Stenzel, P. Vana, C. Barner-Kowollik, Macromolecules 2005, 38, 9497-9508. DOI: 10.1021/ma051485k[005] Laser Single Pulse Initiated RAFT Polymerization for Assessing Chain-Length Dependent Radical Termination Kinetics
M. Buback, T. Junkers, P. Vana, Macromol. Rapid Commun. 2005, 26, 796-802. DOI: 10.1002/marc.200500067[004] PLP-ESR Monitoring of Mid-chain Radicals in n-Butyl Acrylate Polymerization
R.X.E. Willemse, A.M. van Herk, E. Panchenko, T. Junkers, M. Buback, Macromolecules 2005, 38, 5098-5103.DOI: 10.1021/ma050198d[003] Tuning of Cross-Linking and Mechanical Properties of Laser Deposited Poly(Methyl Methacrylate) Films
E. Süske, T. Scharf, H.U. Krebs, E. Panchenko, T. Junkers, M. Egorov, M. Buback, H. Kijewski, H., J. Appl. Phys. 2005, 97, No. 063501. DOI: 10.1063/1.1850609[002] Termination Kinetics of di-n-Butyl Itaconate Free-Radical Polymerization Studied via the SP-PLR-ESR Technique
M. Buback, M. Egorov, T. Junkers, E. Panchenko, Macromol. Chem. Phys. 2005, 206, 333-341. (see Journal Cover Page) DOI: 10.1002/macp.2004003582004
[001] Free-Radical Termination Kinetics Studied Using a Novel SP-PLP-ESR Technique
M. Buback, M. Egorov, T. Junkers, E. Panchenko, Macromol. Rapid Commun. 2004, 25, 1004-1009. DOI: 10.1002/marc.200400050